MXene的功能化改性及其应用研究进展

刘超; 李茜; 郝丽芬; 邓燕平; 殷青; 鲍艳

doi:10.13801/j.cnki.fhclxb.20201218.003

MXene的功能化改性及其应用研究进展

doi: 10.13801/j.cnki.fhclxb.20201218.003

刘超^1, ,,
李茜^2,,
郝丽芬^2,,
邓燕平^2,,
殷青^2,,
鲍艳^3,

1.
陕西科技大学　陕西省轻化工助剂化学与技术协同创新中心，西安 710021
2.
陕西科技大学　化学与化工学院，西安 710021
3.
陕西科技大学　轻工科学与工程学院，西安 710021

基金项目: 国家自然科学基金(22008145)

详细信息

通讯作者:
刘超，讲师，硕士生导师，研究方向为聚合物基纳米复合摩擦材料的构筑、水性功能涂饰材料的设计与应用研究等　E-mail：lc1010158@163.com

中图分类号: TB34
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- 被引次数: 0
出版历程
- 收稿日期: 2020-10-14
- 录用日期: 2020-12-14
- 网络出版日期: 2020-12-18
- 刊出日期: 2021-04-08

Research progress of functional modification of MXene and its applications

LIU Chao^{1
, ,},
LI Xi^2
,,
HAO Lifen^2
,,
DENG Yanping^2
,,
YIN Qing^2
,,
BAO Yan^3
,

1.
Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry and Technology, Shaanxi University of Science and Technology, Xi′an 710021, China
2.
College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi′an 710021, China
3.
College of Bioresources Chemical and Matrials Engineering, Shaanxi University of Science and Technology, Xi′an 710021, China

摘要

摘要: MXene是一类新型的具有类石墨烯结构的二维材料，由过渡金属碳化物、氮化物或碳氮化物构成。MXene具有优异的物理化学性质，如较大的比表面积、良好的导电性、优异的催化性、优良的自润滑性能、丰富的表面官能团等，在多个领域展现出广阔的潜在应用前景。本文针对MXene片层易叠加及其与聚合物基体相容性较差等问题，对MXene表面功能化改性的研究进展进行了综述，包括有机物、无机物、有机-无机杂化改性等，并总结了其在储能、催化和摩擦学等领域的应用研究，展望了其未来的研究方向和发展前景。
- MXene /
- 类石墨烯 /
- 二维材料 /
- 功能化改性 /
- 应用
Abstract: MXene is a novel kind of two-dimensional material with similar structure with graphene, which is composed of transition metal carbide, nitride or carbonitrides. Usually, it has excellent physical and chemical properties, such as large specific surface area, good electrical conductivity, excellent catalysis, excellent self-lubricating property, and abundant surface functional groups, thus showing broad application prospects in varied fields. In this paper, in view of easy stacking of MXene nanosheets and the poor compatibility with polymer matrix, the research progress of MXene surface functional modification was reviewed, including organic, inorganic and organic-inorga-nic hybrid modification methods. It also summarized the applications research progress of MXene in the fields of energy storage, catalysis and tribology, as well as prospected the future research direction.
- MXene /
- similar structure with graphene /
- two-dimensional material /
- functional modifications /
- applications

HTML全文

图 1 聚吡咯(PPy)改性Ti₃C₂T_x MXene的示意图^[14]

Figure 1. Schematic diagram of polypyrrole (PPy) modified Ti₃C₂T_x MXene^[14]

下载: 全尺寸图片幻灯片

图 2 NiO/Ti₃C₂纳米材料的合成过程示意图^[18]

Figure 2. Schematic describing the synthesis process of NiO/Ti₃C₂ nanomaterials^[18]

下载: 全尺寸图片幻灯片

图 3 MXene/碳纳米角(CNHs)/β-环糊精(β-CD)-金属-有机框架材料(MOF)的合成路线和对多菌灵(CBZ)的传感示意图^[27]

Figure 3. Synthetic route of MXene/carbon nanohorns (CNHs)/β-cyclodextrin (β-CD)-metal-organic framework (MOF) and schematic diagram of sensing for carbendazim (CBZ)^[27]

CTAB—Cetyltrimethyl ammonium bromide; HF—Hydrofluoric acid; CBZ—Carbendazim; DPV—Diﬀerential pulse voltammetry; GCE—Glassy carbon working electrode; SCE—Saturated calomel electrode

下载: 全尺寸图片幻灯片

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