基于氧化石墨烯及其复合材料的纺织品抗菌整理研究进展

张思雨; 赵立环; 刘斯璐; 巩继贤; 陈磊

doi:10.13801/j.cnki.fhclxb.20201202.002

基于氧化石墨烯及其复合材料的纺织品抗菌整理研究进展

doi: 10.13801/j.cnki.fhclxb.20201202.002

天津工业大学　纺织科学与工程学院，天津 300387

基金项目: 国家留学基金管理委员会资助项目〔2018〕10038号

详细信息

通讯作者:
赵立环，博士，讲师，硕士生导师，研究方向为医用功能型纺织品　 E-mail：zhaolihuan@tiangong.edu.cn

中图分类号: TS195.5
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- 被引次数: 0
出版历程
- 收稿日期: 2020-09-21
- 录用日期: 2020-11-14
- 网络出版日期: 2020-12-03
- 刊出日期: 2021-04-08

Research progress of antibacterial finishing of textiles based on graphene oxide and its composite materials

School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China

摘要

摘要: 作为石墨烯的含氧衍生物，氧化石墨烯(GO)因其优异的物理、化学性能而受到广泛关注。本文首先分析了GO的抗菌机制，其次总结了GO与金属粒子、金属氧化物和有机物的抗菌复合材料的研究进展，然后探讨了基于GO及其复合材料的纺织品抗菌整理方法及其优缺点，最后提出了GO及其复合材料在纺织品抗菌整理方面的研究方向。
- 氧化石墨烯 /
- 复合材料 /
- 纺织品 /
- 抗菌整理 /
- 纳米粒子
Abstract: Graphene oxide (GO), as an oxygen-containing derivative of graphene, has attracted wide attention for its excellent physical and chemical properties. In this paper, the antibacterial mechanism of graphene oxide was analyzed; the research progress of antibacterial composite materials of graphene oxide and metal particles, metal oxides and organics were summarized; and the antibacterial finishing methods and their advantages and disadvantages of textiles based on graphene oxide and its composite materials were discussed again. Finally, the research trends of graphene oxide and its composite materials in textile antibacterial finishing were further analyzed.
- graphene oxide /
- composites material /
- textiles /
- antibacterial finishing /
- nanoparticles

HTML全文

图 1 石墨烯/氧化石墨烯(GO)抗菌机制的模型之一 (a)、观察氧化石墨烯-LB膜的抗菌活性 (b)^[18]

Figure 1. One of the proposed models for the antibacterial mechanism of graphene/graphene oxide (GO) (a) , observed antibacterial activity of GO-LB films (b)^[18]

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图 2 GO与病原菌的相互作用图式及GO对细菌病原和真菌孢子的抑菌作用机制^[19]

Figure 2. Scheme of interaction between GO and pathogens and the toxicity mechanisms of antibacterial activity of GO against bacterial phypathogens and fungal spores^[19]

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图 3 石墨烯抽取细菌细胞膜磷脂的过程^[21]

Figure 3. Graphene extraction of phospholipids from bacterial cell membranes^[21]

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图 4 ZIF-8的合成 (a) ，ZIF-8的纳米粒子在ZIF-8内部原位生长 (b)^[33]

Figure 4. Synthesis of ZIF-8 (a) , in situ growth of ZIF-8@GO with the nanoparticles carried inside ZIF-8 (b)^[33]

RT—Room temperature; TEA—Triethanolamine

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表 1 GO、GO-CS、GO-Ag 和 GO-CS-Ag 纳米复合材料对革兰氏阳性和革兰氏阴性菌株的最低抑菌浓度值^[28]

Table 1. MIC values of GO、GO-CS、GO-Ag and GO-CS-Ag nanocomposite againstgram-positive and gram-negative bacterial strains

Microorganisms	MIC (mean±SD)/(μg·mL⁻¹)
Microorganisms	GO	GO-CS	GO-Ag	GO-CS-Ag
S. aureus	50±0.32	45±0.30	20±0.33	10±0.32
S. mutans	45±0.21	40±0.25	25±0.35	10±0.35
E. coli	35±0.36	30±0.24	15±0.41	8±0.41
K. pneumonia	35±0.32	30±0.36	15±0.42	8±0.42
P. aeruginosa	35±0.47	30±0.41	14±0.36	7±0.32
S. typhi	30±0.30	25±0.21	15±0.21	8±0.38
Notes：MIC—Minimum inhibitory concentration; SD—Standard deviation; All experiments were performed in triplicates and reported as mean±SD. Antibacterial activity of GO = GO-CS, GO-Ag and GO-CS-Ag were significantly different from each other at p ≤ 0.05.

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表 2 GO复合材料纺织品抗菌整理方法

Table 2. Summary of antibacterial finishing methods for textiles based on GO composite materials

Antibacterial finishing method	Basic rules	Advantages	Disadvantages
Electrospinning	Jet spinning of polymer solution or melt in strong electric field	Controllable process, many kinds of spinnable materials, low cost and simple preparation devices	Graphene oxide is easy to agglomerate and it is difficult to spin uniformly
Dipping	Finishing agent is formulated into a solution, soaked into the fabric, pressed, and baked	Less impact on the mechanical properties of the fabric	Consumption of antibacterial materials is large, the bonding fastness is low, and the uniformity is difficult to control
Coating method	Antibacterial material is diluted and added with additives, and then evenly coated on the surface of the fabric	Simple method and has low requirements for fabric quality	Thickness of the fabric increases after coating, which has a greater impact on the feel and breathability of the fabric
Electrostatic layer-by-layer self-assembly method	Two materials with opposite charges are alternately deposited on the surface of the fabric in a polyelectrolyte solution	Poor stability	High adsorption capacity and controllable thickness of finished fabric
Chemical grafting	First, the graphene oxide is chlorinated, and then other materials are covalently grafted onto the graphene oxide	Short occurrence time and strong combination	High requirements for reactant functional groups
In situ reduction	Fabric is coated with graphene oxide, and the graphene oxide is reduced and compounded in a reducing solution	High binding fastness	Has eestrictions on reactive functional groups

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