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Ti基MXene及其复合材料在金属离子电池中的进展

刘浩 姚卫棠

刘浩, 姚卫棠. Ti基MXene及其复合材料在金属离子电池中的进展[J]. 复合材料学报, 2020, 37(12): 2984-3003. doi: 10.13801/j.cnki.fhclxb.20200717.001
引用本文: 刘浩, 姚卫棠. Ti基MXene及其复合材料在金属离子电池中的进展[J]. 复合材料学报, 2020, 37(12): 2984-3003. doi: 10.13801/j.cnki.fhclxb.20200717.001
LIU Hao, YAO Weitang. Research progress of Ti-based MXene and its composites in metal-ion batteries[J]. Acta Materiae Compositae Sinica, 2020, 37(12): 2984-3003. doi: 10.13801/j.cnki.fhclxb.20200717.001
Citation: LIU Hao, YAO Weitang. Research progress of Ti-based MXene and its composites in metal-ion batteries[J]. Acta Materiae Compositae Sinica, 2020, 37(12): 2984-3003. doi: 10.13801/j.cnki.fhclxb.20200717.001

Ti基MXene及其复合材料在金属离子电池中的进展

doi: 10.13801/j.cnki.fhclxb.20200717.001
基金项目: 国家自然科学基金(21671160)
详细信息
    通讯作者:

    姚卫棠,博士,教授,博士生导师,研究方向为能源材料储存与转换 E-mail:wtyao@ustc.edu.cn

  • 中图分类号: TB34;TM912

Research progress of Ti-based MXene and its composites in metal-ion batteries

  • 摘要: 二维过渡金属碳(氮或碳氮)化物MXene自2011年首次报告后,其家族成员不断增加,目前已有超过20种MXene被成功合成。凭借独特的层状结构,出色的物理化学性质和可设计的表面官能团特性,MXene被认为是极具潜力的电极材料。近年来,MXene及其复合材料在储能领域进展显著。为此,本文综述了Ti基MXene及其复合材料在Li离子电池和Na离子电池中的研究进展,并结合其制备方法和特性,详细介绍了电池性能提升策略或机制。最后,指出了MXene及其复合材料构建高性能电池面临的挑战,并对未来前景进行了展望。

     

  • 图  1  层状M3AX2晶体结构(a)、单层M3X2的侧视图 (b)和俯视图(c)[21]

    Figure  1.  Crystal structure of layered M3AX2 solid phase (a), side (b) and top (c) views of M3X2 monolayer[21]

    图  2  MXene“粘土”合成及电极制备原理图[30]

    Figure  2.  Schematic of MXene clay synthesis and electrode preparation[30]

    图  3  蚀刻和分层示意图(a)、电化学电池的配置(b)、块状Ti3AlC2(c)、Ti3C2Tx在水中的分散液(d)、Ti3AlC2、Ti3C2Tx和Ti3C2Tx薄膜的XRD图谱(e)[31]

    Figure  3.  Schematic of the etching and delamination process (a), configuration of electrochemical cell (b), optical image of the as-received bulk Ti3AlC2 (c), aqueous dispersion of delaminated Ti3C2Tx (d), XRD patterns of Ti3AlC2, Ti3C2Tx and Ti3C2Tx (e)[31]

    图  4  MXene平行排列的离子迁移(a)、MXene竖直排列的离子迁移(b)[75]

    Figure  4.  Ion transport in horizontally stacked (a) and vertically aligned (b) Ti3C2Tx MXene films[75]

    图  5  Ti3C2纳米带合成过程(a)及Ti3AlC2(b)、 Ti3C2纳米片(c)、三维多孔Ti3C2(d)的SEM图像[80]

    Figure  5.  Schematic of synthesis of Ti3C2 nanoribbons (a) and SEM images of the corresponding Ti3AlC2 (b) , Ti3C2 nanosheets (c) andTi3C2 nanoribbons (d)[80]

    图  6  Ti3C2Tx皱缩后SEM图像(a)、Ti3C2Tx加入NaOH后引起结絮(b)[80]、3D多孔MXene泡沫制备过程(c)[81]

    Figure  6.  SEM images of Ti3C2Tx flocculated networks (a), photographs of Ti3C2Tx MXene colloidal suspensions (b)[80], schematic illustration of the preparation process of 3D porous MXene foam (c)[81]

    图  7  碳纳米纤维(CNF)“桥接”Ti3C2Tx片(a)[83]、多孔Ti3C2Tx-CNT俯视SEM图像(b)和截面SEM图像(c)、Na+和电子在多孔Ti3C2Tx-CNT中迁移(d)[84]

    Figure  7.  Schematic showing the preparation of MXene/carbon nanofiber (CNF) hybrid particles (a), top view (b) and cross-sectional (c) SEM images of porous Ti3C2Tx-CNT, Na+ diffusion and electron transfer within porous Ti3C2Tx-CNT electrodes (d)[84]

    图  8  MXene、rGO和MXene-rGO的合成示意图(a) 、Ti3C2-RGO复合材料倍率性能(b)、Ti3C2-RGO复合材料长循环性能(c)[85]

    Figure  8.  Schematic illustration of the fabrication of the MXene, rGO, and MXene-rGO films (a), rate capability of different samples (b), cycle performance of different samples at 1 A·g−1 (c)[85]

    图  9  GeOx@MXene不同倍率下长循环性能(a)、0.2 C下GeOx@MXene不同温度容量(b)、 −40、−20和60℃时的循环性能(c)、在0.5 C下100次循环后GeOx@MXene电极的TEM图像和Ge、O、Ti、C、F的元素映射(d)[88]

    Figure  9.  Cycling performance of the battery with GeOx@MXene (a), GeOx@MXene at differenttemperatures under 0.2 C (b), corresponding cyclingperformance at −40, −20 and 60℃, respectively (c), TEM images and element mappings of Ge, O, Ti, C and F of the GeOx@MXene electrode after 100 cycles at 0.5 C (d)[88]

    图  10  SiO2/MXene微球制备过程(a)、SiO2/MXene微球的SEM图像(b)

    Figure  10.  Schematic diagram for the synthesis process of SiO2/MXene microspheres (a), SEM image of SiO2/MXene (b)

    图  11  Ti 2p的XPS图谱(a)、Ti 2p的XPS对应的定量分析结果 (b)、Ti3C2的Bader电荷计算结果(c)、Co3O4@Ti3C2Tx的Bader电荷结果(d)[94]

    Figure  11.  XPS spectra of Ti 2p (a), percentages of various atomic Ti species (Ti, Ti2+, Ti3+ and Ti—O) of the m-Ti3C2Tx, f-Ti3C2Tx and H-4(Co3O4@Ti3C2Tx) (b), bader charge results of two-layer bare Ti3C2 (c) and Co3O4@Ti3C2Tx (d)[94]

    图  12  Fe3O4@Ti3C2Tx电极分别经过30次循环(a)、300次循环(b)、1 000次循环(c)的SEM图像和经循环后Fe3O4@Ti3C2Tx电极原位XRD图谱(d)[95]

    Figure  12.  SEM images of the Fe3O4@Ti3C2Tx electrode after 30 cycles (a), 300 cycles (b) , and 1000 cycles (c) and ex-situ XRD pattern of Fe3O4@Ti3C2Tx electrode after 30, 300 and 1000 cycles (d)[95]

    图  13  Li在 MoS2(a)和MoS2/Mo2TiC2Ox(b)上的吸附位点、对应吸附位点的结合能(c)、MoS2/Mo2TiC2Tx倍率性能(d)、MoS2(e)和 Mo2TiC2O2(f)上最稳定的吸附构型和结合能、MoS2/Mo2TiC2Tx制备过程(g)[96]

    Figure  13.  Adsorption sites for Li on MoS2 (a) and MoS2/Mo2TiC2Ox (b), binding energies of Li on the surface of MoS2 and MoS2/Mo2TiC2Ox (c), rate performance for MoS2/Mo2TiC2Tx (d), the most stable adsorption configurations and binding energies of Li2S on MoS2 (e) and Mo2TiC2O2 (f), schematic illustration of the preparation of MoS2/Mo2TiC2Tx (g)[96]

    图  14  真空辅助抽滤合成MXene/SnS2(a)、不同比例MXene/SnS2的循环性能(b)和倍率性能(c)[98]

    Figure  14.  Schematic illustration of the preparation of MXene/SnS2 composite by vacuum-assisted filtration(a), cycling performance (b) and rate performance (c) of MXene/SnS2 10∶1, 5∶1, 2∶1 and MXene[98]

    图  15  BPQD/Ti3C2合成过程(a)、BPQD/Ti3C2倍率性能(b)和循环性能(c)、BPQD/Ti3C2电极放电过程中的DMES机制(d)[101]

    Figure  15.  Schematic illustration of the formation process of the BPQD/Ti3C2 composite (a), rate performance of the BPQD/Ti3C2 composite electrode followed with a cycling performance at 100 mA·g −1 (b), long cycling performance of the BPQD/Ti3C2 composite electrode at a high current rate of 1 000 mA·g −1 (c), schematic illustration showing the DMES mechanism involved in the discharge process of the BPQD/Ti3C2 electrodes (d)[101]

    图  16  BP/Ti3C2Tx倍率性能(a)、 BP/Ti3C2Tx长循环性能(b)[102]

    Figure  16.  Rate performances of BP/Ti3C2Tx (a), cycling performance of BP/Ti3C2Tx (b)[102]

    图  17  NaTi1.5O8.3制备过程[105](a)、TiS2@CPVP制备过程(b)、TEM图像(c)、倍率性能(d)和循环性能(e)[106]

    Figure  17.  Schematic of the fabrication of NaTi1.5O8.3[105](a), schematic of the synthesis of PVP derived carbon confined TiS2 nanosheets (b), TEM image (c), rate capability (d) and long cycling performance (e) of TiS2@CPVP[106]

    图  18  CoO/Co2Mo3O8@MXene的制备过程(a)、倍率性能(b)和长循环性能(c)[109]

    Figure  18.  Schematic illustration showing the synthesis of CoO/Co2Mo3O8@MXene (a) , rate capabilities (b) and cycling behaviors (c) of CoO/Co2Mo3O8@MXene[109]

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出版历程
  • 收稿日期:  2020-05-21
  • 录用日期:  2020-07-08
  • 网络出版日期:  2020-07-17
  • 刊出日期:  2020-12-15

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