Effect of graphene coating on heat transfer of anti-/deicing component for helicopter rotor
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摘要: 采用水性和油性石墨烯涂层对复合材料防/除冰组件进行测温及防/除冰实验。针对直升机旋翼对结冰的敏感等特点,提出了旋翼防/除冰组件包铁表面涂覆石墨烯涂层改性传热性能的方法,从而提高旋翼防/除冰组件除冰效率。为验证石墨烯涂层对防/除冰组件传热效率具有显著的提高作用,采用搭建的除冰实验平台并对涂覆的旋翼防/除冰组件进行传热实验及除冰实验。结果表明,石墨烯涂层对提高防/除冰组件的传热性能具有显著作用。同时,采用油性石墨烯涂层和水性石墨烯涂层分别进行传热测试,研究表明油性石墨烯涂层升温速率高于水性石墨烯涂层,且油性石墨烯涂层平均传热速率为0.021℃/s,瞬时最大传热速率为0.083℃/s,均高于水性石墨烯涂层,说明油性石墨烯涂层的防/除冰效果优于水性石墨烯。最后,通过改变喷涂工艺控制石墨烯涂层厚度进行研究,研究发现随着石墨烯涂层厚度的增加,涂层的导热系数逐渐减小,该实验结果验证了Balandin等推导的热导率公式中石墨烯热导率与片层厚度之间的反比例关系。Abstract: The temperature measurements and anti-/deicing experiments of the composite anti-/deicing component were performed with water-based and oil-based graphene coating. In view of the sensitivity of helicopter rotor to icing, a method of modifying the heat transfer performance of rotor anti-/deicing component with graphene coating on the iron surface was proposed to improve the efficiency of anti-/deicing component. In order to verify the effect of graphene coating on the heat transfer efficiency, the temperature measurements and deicing experiments of the coated rotor anti-/deicing components were carried out on the deicing experimental platform. The experimental results show that the graphene coating has a significant effect on improving the heat transfer performance of anti-/deicing component. Meanwhile, the heat transfer of oil-based graphene coating and water-based graphene coating were tested respectively. The results show that the temperature rise rate of oil-based graphene coating is higher than that of water-based graphene coating, and the average heat transfer rate of oil-based graphene coating is 0.021℃/s, the instantaneous maximum heat transfer rate is 0.083℃/s, which are higher than that of water-based graphene coating. The results indicate that the anti-/deicing effect of oil-based graphene coating is better than that of water-based graphene coating. Finally, by changing the spraying process to control the thickness of graphene coating, it is found that with the increasing of the thickness of graphene coating, the thermal conductivity of the coating gradually decreases. The experimental results verify the inverse proportion relationship between the thermal conductivity of graphene coating and the thickness of the sheet in the thermal conductivity formula deduced by Balandin et al.
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Key words:
- graphene coating /
- heat transfer /
- anti-/deicing /
- spray coat /
- composites
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表 1 不同石墨烯涂层的除冰时间和除冰效率
Table 1. Deicing time and deicing efficiency of different graphene coatings
Test Deicing time/s
(No coating)Deicing time/s
(Water-based graphene)Deicing efficiency/%
(Water-based graphene)Deicing time/s
(Oil-based graphene)Deicing efficiency/%
(Oil-based graphene)1 176 125 28.97↑ 83 52.84↑ 2 185 137 25.94↑ 92 50.27↑ 3 171 119 30.40↑ 78 54.36↑ -
[1] PISCITELLI F, CHIARIELLO A, DABKOWSKI D, et al. Superhydrophobic coatings as anti-icing systems for small aircraft[J]. Aerospace,2020,7(1):2. doi: 10.3390/aerospace7010002 [2] DEKONINCK L H, AHMADI S F, BOREYKO J B. Passive anti-frosting cables[J]. International Journal of Heat and Mass Transfer,2020,146:118808. doi: 10.1016/j.ijheatmasstransfer.2019.118808 [3] QI Y, YANG Z, CHEN T, et al. Fabrication of superhydrophobic surface with desirable anti-icing performance based on micro/nano-structures and organosilane groups[J]. Applied Surface Science,2020,501:144165. doi: 10.1016/j.apsusc.2019.144165 [4] 杨常卫, 胡和平, 马艳玲, 等. 直升机旋翼桨叶防/除冰技术新思路[J]. 直升机技术, 2009(3):47-51. doi: 10.3969/j.issn.1673-1220.2009.03.009YANG C W, HU H P, MA Y L, et al. A new idea on anti-icing and de-icing of helicopter rotor blade[J]. Helicopter Technique,2009(3):47-51(in Chinese). doi: 10.3969/j.issn.1673-1220.2009.03.009 [5] 曹普孙, 张威, 胡偶. 基于CCAR-29附录C的旋翼结冰特性研究[J]. 直升机技术, 2019(3):1-4, 9. doi: 10.3969/j.issn.1673-1220.2019.03.001CAO P S, ZHANG W, HU O. Research for rotor icing property based on CCAR-29 appendix C[J]. Helicopter Technology,2019(3):1-4, 9(in Chinese). doi: 10.3969/j.issn.1673-1220.2019.03.001 [6] OVERMEYER A, PALACIOS J, SMITH E. Ultrasonic de-icing bondline design and rotor ice testing[J]. AIAA Journal,2013,51(12):2965-2976. doi: 10.2514/1.J052601 [7] THOMAS S K, CASSONI R P, MACARTHUR C D. Aircraft anti-icing and de-icing techniques and modeling[J]. Journal of Aircraft,1996,33(5):841-854. [8] 蔺瑞, 颜正国, 刘涛, 等. 60 t钢包浇注过程中汇流旋涡形成机理[J]. 过程工程学报, 2010, 10(4):655-659.LIN R, YAN Z G, LIU T, et al. Modeling formation mechanism of vortex during steel casting in a 60 t ladle[J]. The Chinese Journal of Process Engineering,2010,10(4):655-659(in Chinese). [9] WROBLEWSKI G, KIELBASINSKI K, SWATOWSKA B, et al. Carbon nanomaterials dedicated to heating systems[J]. Circuit World,2015,41(3):102-106. doi: 10.1108/CW-05-2015-0021 [10] PROLONGO S G, MORICHE R, ROSARIO G D, et al. Joule effect self-heating of epoxy composites reinforced with graphitic nanofillers[J]. Journal of Polymer Research,2016,23(9):189. doi: 10.1007/s10965-016-1092-4 [11] RAJI A R O, VARADHACHARY T, NAN K, et al. Composites of graphene nanoribbon stacks and epoxy for joule heating and deicing of surfaces[J]. ACS Applied Materials & Interfaces,2016,8(5):3551-3559. [12] WANG T, ZHENG Y, RAJI A R O, et al. Passive anti-icing and active deicing films[J]. ACS Applied Materials & Interfaces,2016,8(22):14169-14173. [13] 秦红梅, 邓超然, 李明专, 等. 石墨烯纳米薄片-SiO2/天然橡胶复合材料的导电导热性能[J]. 复合材料学报, 2019, 36(11):2683-2691.QIN H M, DENG C R, LI M Z, et al. Electrical and thermal properties of nano graphene sheets-SiO2/natural rubber composites[J]. Acta Materiae Compositae Sinica,2019,36(11):2683-2691(in Chinese). [14] 周宏, 朴明昕, 李芹, 等. 氧化石墨烯纳米片/环氧树脂复合材料的制备与性能[J]. 复合材料学报, 2015, 32(5):1309-1315.ZHOU H, PIAO M X, LI Q, et al. Preparation and properties of graphene oxide nanosheeets/epoxy composites[J]. Acta Materiae Compositae Sinica,2015,32(5):1309-1315(in Chinese). [15] ZHOU W, MAO L, HU X, et al. An optimized graphene oxide self-assembly surface for significantly enhanced boiling heat transfer[J]. Carbon,2019,150:168-178. doi: 10.1016/j.carbon.2019.04.119 [16] PRAVEEN B, SURESH S, PETHURAJAN V. Heat transfer performance of graphene nano-platelets laden micro-encapsulated PCM with polymer shell for thermal energy storage based heat sink[J]. Applied Thermal Engineering,2019,156:237-249. doi: 10.1016/j.applthermaleng.2019.04.072 [17] ZHOU Y, CUI X, WENG J, et al. Experimental investigation of the heat transfer performance of an oscillating heat pipe with graphene nanofluids[J]. Powder Technology,2018,332:371-380. doi: 10.1016/j.powtec.2018.02.048 [18] NADDAF A, HERIS S Z, POULADI B. An experimental study on heat transfer performance and pressure drop of nanofluids using graphene and multi-walled carbon nanotubes based on diesel oil[J]. Powder Technology,2019,352:369-380. doi: 10.1016/j.powtec.2019.04.078 [19] 秦国锋, 张婧婧, 徐子威, 等. BN纤维对石墨烯微片/聚丙烯复合材料导热绝缘性能的影响[J]. 复合材料学报, 2020, 37(3):546-552.QIN G F, ZHANG J J, XU Z W, et al. Effect of BN fiber on thermal conductivity and insulation properties of graphene nanoplatelets/polypropylene composites[J]. Acta Materiae Compositae Sinica,2020,37(3):546-552(in Chinese). [20] ZHANG Q, YU Y, YANG K, et al. Mechanically robust and electrically conductive graphene-paper/glass-fibers/epoxy composites for stimuli-responsive sensors and Joule heating deicers[J]. Carbon,2017,124:296-307. doi: 10.1016/j.carbon.2017.09.001 [21] ZANJANI J S M, OKAN B S, MENCELOGLU Y Z, et al. Nano-engineered design and manufacturing of high-performance epoxy matrix composites with carbon fiber/selectively integrated graphene as multi-scale reinforcements[J]. RCS Advances,2016,6(12):9495-9506. [22] ZANJANI J S M, OKAN B S, PAPPAS P N, et al. Tailoring viscoelastic response, self-heating and deicing properties of carbon-fiber reinforced epoxy composites by graphene modification[J]. Composites Part A: Applied Science and Manufacturing,2018,106:1-10. doi: 10.1016/j.compositesa.2017.12.008 [23] LIU Y, LI Y, YANG Y, et al. Preparation and properties of graphene oxide–carbon fiber/phenolic resin composites[J]. Carbon,2013,52:624. [24] KONG Q Q, LIU Z, GAO J G, et al. Hierarchical graphene-carbon fiber composite paper as a flexible lateral heat spreader[J]. Advanced Functional Materials,2014,24(27):4222-4228. doi: 10.1002/adfm.201304144 [25] CHEN L, ZHANG Y, WU Q. Heat transfer optimization and experimental validation of anti-icing component for helicopter rotor[J]. Applied Thermal Engineering,2017,127:662-670. doi: 10.1016/j.applthermaleng.2017.07.169 [26] CHEN L, ZHANG Y, WU Q, et al. Numerical simulation and optimization analysis of anti-/de-icing component of helicopter rotor based on big data analytics[M]//ZHANG L, SONG X, WU Y. Theory, methodology, tools and applications for modeling and simulation of complex systems. Singapore: Springer, 2016. [27] BALANDIN A A, GHOSH S, BAO W, et al. Superior thermal conductivity of single-layer graphene[J]. Nano Letters,2008,8(3):902-907. doi: 10.1021/nl0731872