Preparation and properties of cellulose nanofiber-reduced graphene oxide/polyaniline composite aerogels as flexible electrodes
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摘要: 利用高长径比的纤维素纳米纤丝(CNF)与片层结构的氧化石墨烯(GO)形成的CNF-GO复合水凝胶经抗坏血酸还原制备出CNF-还原氧化石墨烯(rGO)复合水凝胶材料。通过冷冻干燥法得到CNF-rGO复合气凝胶,并进一步通过苯胺单体在CNF-rGO复合气凝胶的孔道内原位聚合制备出CNF-rGO/聚苯胺(PANI)气凝胶柔性电极复合材料。研究了不同苯胺、CNF和GO的质量比对CNF-rGO/PANI气凝胶柔性电极复合材料的结构形貌和电化学性能的影响。结果表明,苯胺原位聚合后所得CNF-rGO/PANI复合气凝胶仍具有紧密的三维多孔网络结构。与rGO/PANI气凝胶电极复合材料相比,CNF-rGO/PANI气凝胶电极复合材料具有更理想的电容行为。当CNF与GO质量比为60∶40,PANI添加量为0.1 mol时,CNF-rGO/PANI气凝胶电极复合材料比电容可达85.9 Fg-1,且其电化学性能几乎不受弯曲程度的影响,展现出了良好的柔韧性和电化学性能。Abstract: The cellulose nanofiber-reduced graphene oxide (CNF-rGO) composite hydrogel was prepared by ascorbic acid reduction of CNF-graphene oxide (GO) composite hydrogel which was obtained from CNF with high aspect ratio and GO with nanosheet. By freeze-drying method, CNF-rGO composite aerogel was obtained. By the in situ polymerization of aniline monomer, CNF-rGO/polyaniline (PANI) composite aerogels as flexible electrode materials was prepared. The effects of different dosage mass ratio of aniline, CNF and rGO on the morphology, structure and electrochemical properties of CNF-rGO/PANI aerogels electrode composites were studied. The results show that the CNF-rGO/PANI composite aerogels still have relatively close 3D network structure after in situ polymerization of aniline. Compared with rGO/PANI aerogel eletrode composites, the CNF-rGO/PANI aerogel eletrode composites have more excellent capacitance behavior. When the mass ratio of CNF and GO is 60:40 and the amount of PANI is 0.1 mol, the specific capacitance of the CNF-rGO/PANI aerogel electrode composites is 85.9 Fg-1, and its electrochemical properties are hardly affected by bending degree. So, the CNF-rGO/PANI aerogel eletrode composites show good electrochemical performance and excellent flexibility.
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Key words:
- flexible electrode composites /
- cellulose nanofiber /
- polyaniline /
- graphene /
- composite aerogels
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