Aging mechanism and equivalent acceleration relationship of G827/3234 composite in the marine environment
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摘要: 开展了G827/3234复合材料的实验室加速老化试验和实海随舰自然暴露试验,借助万能试验机、光学显微镜、SEM、DMA、FTIR等设备和技术,观测了老化前后G827/3234试件的表面及断口形貌、力学性能、组织成分等;改进了G827/3234复合材料自然老化的强度中值曲线回归分析方法,基于强度保持率确定了加速老化对自然老化的当量加速关系并加以验证。结果表明:加速老化1个月后,G827/3234的弯曲强度和弯曲模量分别下降1.43%和4.45%,层间剪切强度降幅为8.80%,抗疲劳性能基本不变,玻璃化转变温度下降6.2℃,内耗增大,储能模量下降约5 GPa;得到了其加速老化机制及在海洋环境中自然老化时的强度中值方程;确定了加速老化对自然老化的当量系数为4.52,二者老化机制基本一致,所得系数有效、可用。Abstract: The accelerated aging test in lab and natural exposure test on ship in the marine environment for G827/3234 composite were carried out.By using the universal testing machine, optical microscope, SEM, DMA, FTIR and so on, the surface and fracture morphology, mechanical property and composition of G827/3234 composite were observed and measured before and after aging.The regression analysis method for the strength median curve of G827/3234 under the natural aging condition was improved, and the equivalent accelerated relationship between the accelerated aging and natural aging was obtained based on the strength retention rate and it was verified. The results show that, after one month of accelerated aging, the flexural strength and flexural modulus of G827/3234 composite are decreased by 1.43% and 4.45%, the decline of interlaminar shear strength is 8.80%, the anti-fatigue property is essentially the same, the glass transition temperature is decreased by 6.2℃, the in ternal friction increases and the storage modulus is decreased by about 5 GPa.The mechanism in the accelerated aging and the strength median equation in the natural aging under the marine environment are given out.The equivalent coefficient of accelerated aging to natural aging is 4.52.The aging mechanism of the two are basically the same and the coefficient is proved to be effective and available.
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Key words:
- marine environment /
- composite /
- mechanical property /
- aging /
- equivalent acceleration
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