共聚尼龙纤维网纱增韧碳纤维/环氧树脂复合材料超低温作用后的层间结构与性能

Interlaminar structure and properties of carbon fiber/epoxy composites toughened with copolymerized nylon fiber veil after cryogenic treatment

  • 摘要: 本文通过自主搭建超低温/室温循环研究平台,探究了超低温浸泡时间和超低温/室温循环次数对碳纤维/环氧树脂(CF/EP)复合材料各项力学性能的影响。之后将不同面密度共聚尼龙纤维网纱(PAV)插入到复合材料层间,研究在液氮中超低温浸泡16 h后复合材料层间韧性的变化。结果表明,未增韧情况下超低温浸泡16 h后CF/EP复合材料的Ⅰ型层间断裂韧性(GⅠC)、Ⅱ型层间断裂韧性(GⅡC)、拉伸强度和弯曲强度分别下降了46.2%、22.9%、17.7%和3.2%。而当插入面密度为8 gsm的PAV时,与未增韧样相比CF/EP复合材料的GⅠC在室温下和超低温浸泡16 h后分别提升了49.1%和114.0%;当插入面密度为24 gsm的PAV时,增韧样的GⅡC相比于未增韧样在室温下和超低温浸泡16 h后分别提升了140.2%和178.0%。此外PAV的插入并未对CF/EP复合材料的弯曲性能和层间剪切强度造成明显影响。研究表明,PAV的增韧机制主要是尼龙树脂的拔出、基体塑性形变以及引发裂纹的偏转。本研究改善了超低温处理后的CF/EP复合材料层间韧性,对推动超低温贮箱复合材料化进程具有积极意义。

     

    Abstract: In this paper, a research platform for cryogenic/room temperature cycles was built to explore the effects of cryogenic immersion time and cryogenic/room temperature cycle times on the mechanical properties of carbon fiber/epoxy(CF/EP)composites. Then, copolymerized nylon fiber veil (PAV) with different areal densities was inserted into the interlaminar of the composites, and the interlaminar toughness of the composites was studied after 16 h of cryogenic immersion in liquid nitrogen. The results demonstrate that the interlaminar fracture toughness of mode I(GⅠC), mode Ⅱ(GⅡC), tensile strength and flexural strength of CF/EP composites decline by 46.2%, 22.9%, 17.7% and 3.2%, after 16 h of cryogenic immersion without toughening. The GⅠC of CF/EP composites is increased by 49.1% and 114.0% at room temperature and after 16 h of cryogenic immersion, respectively, when PAV with 8 gsm areal densities were inserted. The GⅡC is increased by 140.2% and 178.0% at room temperature and after 16 h of cryogenic immersion, when PAV with 24 gsm areal densities were inserted. In addition, the insertion of PAV didn't significantly affect the flexural properties and interlaminar shear strength of CF/EP composites. Our findings suggest that the toughening mechanism of PAV is mainly the pull-out of nylon resin, plastic deformation of matrix, and the deflection of initiating cracks. This study improves the interlayer toughness of CF/EP composites after cryogenic treatment, which is of positive significance for promoting the compositing process of cryogenic fuel tanks.

     

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