轧制T2Cu-1060Al-T2Cu复合板的界面结构与力学性能

Interfacial Structure and Mechanical Properties of Rolled T2Cu-1060Al-T2Cu Composite Sheets

  • 摘要: 铜制药筒/弹壳成本高且受我国铜储量限制,高性能铜铝复合板可作为替代材料。本文研究轧制工艺对T2Cu-1060Al-T2Cu复合板组织性能影响规律。复合板TX/a%-TY/b%代表一道次X℃下、压下量a%,二道次Y℃、压下量b%。轧后层界面扩散层沿轧向发生断裂,相组成从铜到铝仍为Cu9Al4、CuAl及CuAl2。T20/50%-T350/33%扩散层厚度最大(6.9 μm),与组元板间未观察到孔洞。T350/50%与T350/67%的扩散层厚度分别为6.2 μm、5.8 μm,与组元板间孔洞尺寸明显小于T20/50%,说明小压下量多道次热轧能促进界面元素扩散及组元板和扩散层的协调变形。对总压下量为67%的两轧制态,大部分Al晶粒取向为111,靠近界面层的Al微区为101取向,原因是组元板性能差异使Cu层对靠近界面层的Al产生应力约束。轧制态Cu侧Brass织构强度较原始态大幅减弱;T350/67%的织构强度更高,包括Cu侧和靠近界面层Al侧S和Copper织构、远离界面层Al侧的β纤维织构,说明小压下量多道次轧制有助于织构弱化。综上,小压下量多道次热轧可以促进界面扩散,弱化织构,协调界面变形,提高抗拉强度同时不降低伸长率。

     

    Abstract: Copper cartridge casings are costly and restricted by national copper reserves, and high-performance Cu-Al composite plates are promising alternatives. This work explores the rolling process effects on microstructure and properties of T2Cu-1060Al-T2Cu composite plates, in which TX/a%-TY/b% refers to the first pass at X℃ with a% reduction and the second pass at Y℃ with b% reduction. After rolling, the interlayer diffusion layer fractures along the rolling direction, with the phase sequence from Cu to Al being Cu9Al4, CuAl and CuAl2. The T20/50%-T350/33% sample has the thickest diffusion layer of 6.9 μm with no interfacial pores; the diffusion layer thickness of T350/50% and T350/67% is 6.2 μm and 5.8 μm, and their interfacial pores are far smaller than those of T20/50%, indicating that multi-pass hot rolling with small reduction boosts interfacial element diffusion and coordinated deformation of matrix and diffusion layers. For rolled samples with a total reduction of 67%, most Al grains show 111 orientation while interfacial Al presents 101 orientation, owing to Cu-induced stress constraint on interfacial Al from matrix property differences. Rolling greatly reduces the Brass texture intensity on the Cu side; T350/67% has stronger textures including S and Copper textures on Cu and near-interface Al sides and β-fiber texture on distant Al sides, proving small-reduction multi-pass rolling weakens texture. Overall, small-reduction multi-pass hot rolling promotes interfacial diffusion, relieves texture, coordinates interfacial deformation, and improves tensile strength of Cu-Al composite plates without reducing elongation.

     

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