硼掺杂碳点的制备及光学方面的研究进展

Preparation of boron-doped carbon dots and research progress in optics

  • 摘要: 碳点(CDs)作为一种具有广泛应用前景的荧光碳纳米材料,表现出优异的物理、化学和光学性能。目前,杂原子掺杂是公认最有效改善CDs光学性能的方法之一。由于硼原子与碳原子的尺寸相似、电负性相近,并且硼原子还具有优异的吸电子能力,因此硼原子掺杂被认为是进一步改善CDs光学性能的有效方法。本文从硼掺杂CDs的光学性能、不同的合成方法和应用三个方面综述了硼掺杂CDs的研究进展。特别是,详细总结了硼掺杂CDs的不同合成方法及不同的配体选择。此外,还综述了硼掺杂CDs在光学传感器、生物成像和信息安全和防伪方面的潜在应用。最后,我们提出并讨论了硼掺杂CDs的挑战及发展前景。

     

    Abstract: Carbon dots (CDs) are fluorescent carbon nanomaterials with a wide range of applications, showing excellent physical, chemical and optical properties. At present, heteroatom doping is recognized as one of the most effective methods to improve the optical properties of carbon dots. Boron doping is recognized as an effective strategy for further enhancing the optical performance of CDs, owing to the comparable atomic size and electronegativity between boron and carbon atoms, combined with boron's exceptional electron-withdrawing capability. In this paper, the research progress of boron-doped carbon dots is reviewed from three aspects: optical properties, different synthesis methods, and applications. In particular, the different synthesis methods of boron-doped carbon dots and the different ligand selections are summarized in detail. In addition, the potential applications of boron-doped CDs in optical sensors, bioimaging, and information security and anti-counterfeiting are reviewed. Finally, we propose and discuss the challenges and development prospects of boron-doped CDs.

     

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