碳点增强聚合物阻燃性能的研究进展

Research progress on the polymer flame-retardancy enhanced by carbon dots

  • 摘要: 材料阻燃是减少火灾伤亡和财产损失的关键手段。然而,传统阻燃剂在应用中常导致材料力学性能下降,并伴随有毒气体释放、生物累积性等危害,严重限制了其应用范围。碳点(Carbon dots, CDs)作为一种新兴的多功能碳纳米材料,具备优异的分散性、良好的热稳定性、原料来源广泛、环境友好及生物相容性佳等突出优势,将其进行阻燃改性构建的新型纳米复合材料在聚合物防火阻燃领域表现出良好的应用前景。本文综述了CDs及其复合材料的阻燃机制与应用研究进展。首先,在总结CDs的阻燃机制的基础上分析了影响CDs阻燃性能的主要因素。另外,介绍了改性CDs在环氧树脂、聚乙烯醇和棉纺织物等材料中的阻燃应用。最后,展望了CDs阻燃剂的改性技术与功能化策略的发展方向,为开发高效、低毒、环境友好的CDs阻燃聚合物基复合材料提供理论参考与设计思路。

     

    Abstract: Flame retardancy is a key performance for reducing fire casualties and property damage. However, traditional flame retardants often cause a decrease in material mechanical properties, along with hazards such as toxic gas release and bioaccumulation, severely limiting their applications. Carbon dots, as an emerging multifunctional carbon nanomaterial, have outstanding advantages such as excellent dispersibility, good thermal stability, wide raw material sources, environmental friendliness, and good biocompatibility. The new nanocomposite materials constructed by carbon dots have shown promising potential for practical applications in the field of polymer fireproofing. This article reviews the research progress on the flame retardant mechanism and application of carbon dots and their composite materials. Firstly, the main factors affecting the flame retardancy of carbon dots are analyzed on the basis of summarizing the flame retardant mechanism of carbon dots. In addition, the flame retardant applications of modified carbon dots in materials such as epoxy resin, polyvinyl alcohol, and cotton textiles are introduced. Finally, the development direction of modification technology and functionalization strategy for carbon dot flame retardants is discussed, providing theoretical reference and design ideas for the development of efficient, low toxicity, and environmentally friendly polymer-carbon dot flame retardant composite materials.

     

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