羟丙基甲基纤维素-水性聚氨酯改性乳化沥青复合材料拉伸性能

Tensile properties of hydroxypropyl methyl cellulose-waterborne polyurethane modified emulsified asphalt composite

  • 摘要: 为减少传统乳化沥青在道路工程应用中低温易开裂、拉伸性能不足等问题,采用高速剪切法制备羟丙基甲基纤维素-水性聚氨酯改性乳化沥青(HPMC/WP-MEA)复合材料。基于测力延度拉伸性能参数设计、红外光谱、弯曲梁流变(BBR)试验和相关系数等方法,分析水性聚氨酯(WPU)掺量、剪切速率和羟丙基甲基纤维素(HPMC)掺量对其拉伸性能的影响及提升机制。结果表明:WPU掺量与WP-MEA的黏韧性存在强相关性,当WPU掺量为2%时,WP-MEA展现出较好的拉伸性能。剪切速率对WP-MEA整体拉伸性能的影响相对较小,但过高的剪切速率会破坏WPU的分子结构,从而降低WP-MEA的韧性。HPMC显著影响HPMC/WP-MEA复合材料的拉伸性能,HPMC的桥接效应可增强HPMC/WP-MEA的黏韧性,建议HPMC用量为1‰~2‰。通过制备、分析和表征HPMC/WP-MEA复合材料拉伸性能,为高性能、低污染乳化沥青复合材料的研发和性能优化奠定了一定的理论基础。

     

    Abstract: To mitigate issues of traditional emulsified asphalt in road engineering applications, such as easy cracking at low temperatures and insufficient tensile properties, hydroxypropyl methyl cellulose-waterborne polyurethane modified emulsified asphalt (HPMC/WP-MEA) composites were prepared by a high-speed shearing method. This work investigates the effects of waterborne polyurethane (WPU) dosage, shear rate, and hydroxypropyl methyl cellulose (HPMC) dosage on the tensile properties of the composite, as well as the underlying enhancement mechanisms, based on methods including force ductility tensile performance parameter design, fourier transform infrared spectroscopy, bending beam rheometer (BBR) tests, and correlation coefficient analysis. The results indicate that the WPU dosage exhibits a strong correlation with the viscosity-toughness of WP-MEA. When the WPU dosage reaches 2%, WP-MEA demonstrates better tensile properties. The shear rate has a relatively small impact on the overall tensile properties of WP-MEA, but an excessively high shear rate will destroy the molecular structure of WPU, thereby reducing the toughness of WP-MEA. HPMC significantly affects the tensile properties of HPMC/WP-MEA composites, and the bridging effect of HPMC can enhance the viscosity-toughness of HPMC/WP-MEA. It is recommended that the dosage of HPMC be 1‰-2‰. Through the preparation, analysis, and characterization of the tensile properties of HPMC/WP-MEA composites, this work lays a certain theoretical foundation for the research and development as well as performance optimization of high-performance and low-pollution emulsified asphalt composites.

     

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