半水磷石膏聚合物复合材料制备及性能研究

Preparation and properties of Hemihydrate Phosphogypsum Polymer Composites

  • 摘要: 磷石膏是制备无水石膏和半水石膏的重要原材料之一。与无水石膏相比,半水石膏作为聚合物填充粉体具有工艺简单和低能耗的特点。本研究通过熔融挤出共混制备了半水石膏/聚合物复合材料。研究了复合材料的力学性能、热性能、氧化性能、腐蚀性能等性能,并对复合材料微观结构进行了表征。结果表明,半水石膏与聚合物基底有很好的相容性,并且在高掺量下可以达到超分散。半水石膏复合材料质量损失温度5%时温度为350℃。在强酸、强碱和浓盐浸泡后,半水石膏聚丙烯(PP)复合材料质量损失分别为0.024%、0.03%和0.015%。表明复合材料具有较好的耐腐蚀性能。与纯PE比较,半水石膏含量为20%的PE复合材料的拉伸性能提高了26%,半水石膏含量为70%的聚乙烯(PE)复合材料的氧指数提高了8.6%。复合材料的熔体流动速率为10~40 g/10min,半水石膏PE复合材料和半水石膏PP复合材料的热变形温度分别约为90℃和150℃。以上数据表明,该复合材料具有良好的加工性能,半水石膏复合材料也具有良好的耐久性和耐热性能。初步研究了半水石膏PE复合材料在DN400管道中应用,其环刚度为8.2 kN/m2,表明半水石膏PE复合材料在建筑双臂波纹排水管具有很好的应用前景。

     

    Abstract: Phosphogypsum is one of the important raw materials for the preparation of anhydrous gypsum and hemihydrate gypsum. Compared with anhydrite, hemihydrate gypsum as a polymer filling material has a simple preparation process and low energy consumption. This study prepared hemihydrate gypsum/polymer composites by melt blending with polymer as matrix and hemihydrate gypsum as filler. The composite's mechanical properties, thermal properties, oxidation properties, corrosion properties, and microstructure were tested. The results show that hemihydrate gypsum is compatible with the polymer and can reach hyper dispersion at a high dosage. When the mass loss temperature of the hemihydrate gypsum composite is 5%, the temperature is 350℃. After soaking in strong acid, strong alkali and concentrated salt, the mass losses of hemihydrate gypsum Polypropylene (PP) composite materials were 0.024%, 0.03% and 0.015% respectively. It indicates that the composite material has good corrosion resistance. Compared with pure Polyethylene (PE), the tensile properties of PE composites with a hemihydrate gypsum content of 20% have increased by 26%, and the oxygen index of PE composites with a hemihydrate gypsum content of 70% has increased by 8.6%. The melt flow rate of the composite material is 10-40 g/10min. The heat distortion temperatures of the hemihydrate gypsum PE composite material and the hemihydrate gypsum PP composite material are approximately 90℃ and 150℃ respectively. The above data indicate that this composite material has excellent processing performance, and the hemihydrate gypsum composite material also has good durability and heat resistance. The application of hemihydrate gypsum PE composite material in DN400 pipes was preliminarily studied, with a ring stiffness of 8.2 kN/m2, indicating that hemihydrate gypsum PE composite material has a very good application prospect in the double-arm corrugated drainage pipes of buildings

     

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