离子凝胶胶黏剂研究进展

Advances in Ionic Gel Adhesive Research

  • 摘要: 随着对环保和绿色化学的日益重视,传统胶黏剂正逐步被市场淘汰,离子凝胶胶黏剂作为一种新型的粘合材料,成为研究者关注的焦点。本文综述了离子凝胶胶黏剂的制备方法,主要根据聚合物和离子液体形成离子凝胶的方式进行了分类,包括直接混合法、溶剂交换法、原位聚合法三种方法;进一步总结了离子凝胶胶黏剂的黏附性,在不同基材的最高胶合强度可达7.2 MPa、离子导电性、机械性能(拉伸强度可达14.3 MPa,断裂伸长率可到5000%)、生物相容性、自愈合性(室温下10 min快速愈合)和透明性等性能特点;并重点介绍了基于自愈合,生物相容性,自黏附、温敏、导电等多功能胶黏剂的结构设计及其在固态电解质、柔性电子、生物医学、智能穿戴设备和光学器件等应用领域中发挥的作用。为离子凝胶胶黏剂更多元化性能的开发和应用提供借鉴。

     

    Abstract: With the increasing emphasis on environmental protection and green chemistry, traditional adhesives are gradually being phased out of the market. Ionic gel adhesives, as a new type of bonding material, have become the focus of researchers’ attention. This article reviews the preparation methods of ionic gel adhesives, categorizing them mainly based on the ways in which polymers and ionic liquids form ionic gels, including direct mixing, solvent exchange, and in-situ polymerization. Furthermore, the article summarizes the adhesive properties of ionic gel adhesives, noting that the maximum bonding strength can reach 7.2 MPa on different substrates, along with their ionic conductivity, mechanical properties (with tensile strength up to 14.3 MPa and elongation at break reaching 5000%), biocompatibility, self-healing ability (rapid healing within 10 minutes at room temperature), and transparency. Additionally, it highlights the structural design of multifunctional adhesives based on self-healing, biocompatibility, self-adhesion, temperature sensitivity, and conductivity, as well as their roles in applications such as solid-state electrolytes, flexible electronics, biomedicine, smart wearable devices, and optical devices. This provides a reference for the development and application of more diversified properties of ionic gel adhesives.

     

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