BN(h)含量对超声-脉冲电沉积Ni-P-WC-BN(h)镀层摩擦磨损性能的影响

Effect of BN(h) content on the friction and wear properties of ultrasonic-pulse electrodeposited Ni-P-WC-BN(h) coatings

  • 摘要: 为改善材料表面硬度及减磨耐磨性能,利用超声-脉冲电沉积法在20CrMnTi表面制备Ni-P-WC-BN(h)纳米复合镀层,采用X射线衍射分析(XRD)研究镀层物相并估算晶粒大小,扫描电镜(SEM)、能谱分析仪(EDS)、显微硬度仪和激光显微镜等测量手段,分析Ni-P、Ni-P-WC及不同BN(h)浓度下Ni-P-WC-BN(h)纳米复合镀层的表面形貌、组织成分、显微硬度、减磨耐磨性能。结果表明:不同纳米颗粒浓度对复合镀层表面的组织结构有重要影响,纳米复合镀层表面呈现典型的包状结构,适宜浓度的二元纳米颗粒共沉积有效改善了镀层微观形貌。Ni-P-WC-BN(h)纳米复合镀层镀态硬度可达1156 HV1,与Ni-P-WC纳米复合镀层相比,在保证Ni-P-WC纳米复合镀层镀态高硬度的同时,摩擦系数降低22.6%,具有更好的减磨耐磨性能。

     

    Abstract: In order to improve the surface hardness and wear reduction and abrasion resistance of the material, Ni-P-WC-BN(h) nanocomposite coatings were prepared on the surface of 20CrMnTi by using ultrasonic-pulsed electrodeposition method, X-ray diffraction analysis (XRD) was used to study the physical phase of the coatings and estimate the grain size, and scanning electron microscopy (SEM), energy spectrum analyzer (EDS), microhardness tester, and laser microscope were used to analyze the surface morphology, tissue composition, microhardness, and wear reduction performance of Ni-P, Ni-P-WC, and Ni-P-WC-BN(h) nanocomposite coatings with different BN(h) concentrations. The results show that different nanoparticle concentrations have important effects on the organization of the composite coating surface, the surface of the nanocomposite coating shows a typical package structure, and the co-deposition of binary nanoparticles with appropriate concentrations effectively improves the coating microscopic morphology.The hardness of Ni-P-WC-BN(h) nanocomposite coating in the plated state can be up to 1156 HV1, which is comparable to that of the Ni-P-WC nanocomposite coating in terms of guaranteeing the micro hardness of Ni-P-WC nanocomposite coating and its wear-resistance. Compared with Ni-P-WC nanocomposite coating, the coefficient of friction is reduced by 22.6% while ensuring the high hardness of Ni-P-WC nanocomposite coating in the plated state, which has better wear reduction and abrasion resistance.

     

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