从被动增强到主动修复:面向环境老化的CFRP界面工程协同策略研究进展

From Passive Enhancement to Active Repair: Research Progress on the Collaborative Strategy of CFRP Interface Engineering Addressing Environmental Aging

  • 摘要: 碳纤维增强聚合物复合材料(Carbon Fiber Reinforced Polymer Composites,CFRP)因高比强度与可设计性广泛应用于高端装备,但其纤维-基体界面在湿热、盐雾、紫外及热氧环境下的老化行为,影响结构长期服役可靠性。为提升界面耐久性,围绕“老化机理-表征方法-增强技术-修复策略”体系展开综述。解析了四种环境中水分扩散、光解反应与热氧化等不同路径对界面的损伤,并总结了多尺度表征技术在界面性能评估中的应用。梳理了以物理作用力、化学键及界面层结构与过渡效应为主的增强机理,介绍了表面能调节、界面结构强化及接枝功能化的增强策略。鉴于传统改性无法逆转界面损伤,进一步从“被动式”增强转向“主动式”自修复,探讨了类玻璃体、热塑性聚合物、微胶囊和血管系统型界面自修复前沿策略。最后,从“技术枚举”上升至“范式归纳”,界定外援型与本征型修复的原理与特征,剖析了本征型中超分子网络、解离和缔合型修复的机制,为发展“自感知-自诊断-自修复”材料提供理论框架与设计思路。

     

    Abstract: Carbon fiber reinforced polymer composites (CFRP) are widely used in high-performance equipment due to their exceptional specific strength and design flexibility. However, the aging behavior of the fiber-matrix interface under environments such as heat and humidity, salt spray, UV and thermal oxidation affects the long-term service reliability of the structure. To enhance interface durability, a review is provided on the system comprising aging mechanisms, characterization methods, enhancement technologies and repair strategies. The interface damage resulting from various mechanisms, including water diffusion, photolysis and thermal oxidation in four specified environments, is analyzed. The application of multi-scale characterization techniques for evaluating interface performance is also summarized. The enhancement theories, mainly based on physical forces, chemical bonds, interfacial layer structures and transition effects, were systematically reviewed. Furthermore, strategies involving surface energy regulation, interfacial structure strengthening and graft functionalization were introduced. Given that traditional modifications cannot reverse interface damage, the focus has shifted from ''passive'' enhancement to ''active'' self-repair. Advanced self-repair strategies for the interface, including vitreoid materials, thermoplastic polymers, microcapsules and vascular systems, are explored. Finally, the discussion shifts from ''technology enumeration'' to ''paradigm induction'', defining the principles and characteristics of extrinsic and intrinsic repair. The mechanisms of intrinsic repair, including supramolecular networks, dissociation and association, are analyzed, providing a theoretical framework and design concepts for the development of ''self-sensing, self-diagnosis, self-repair'' materials.

     

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