酸热环境下CFRP力学性能退化机制

Degradation mechanism of CFRP mechanical properties in acid thermal environment

  • 摘要: 碳纤维增强树脂基复合材料(CFRP)因高比吸能、高比强度及高比模量优势,已广泛应用于航空航天等领域。但CFRP长期服役中难免暴露于酸雨等腐蚀环境,其在酸热耦合环境下的性能演化规律缺乏深入系统研究,成为制约其在复杂工况可靠应用的关键瓶颈。为探究酸热环境下CFRP的力学性能退化机制,设计了CFRP的酸热老化试验,并开展材料力学性能测试。结果表明,酸热环境会引发基体吸水降解与纤维-基体界面弱化,导致CFRP的拉伸强度反常升高,纵向、横向拉伸强度分别提升93.85%和7.14%,反映出碳纤维主导的载荷传递机制;而纵向、横向压缩强度分别降低39.96%和34.14%,主要原因是酸腐蚀导致CFRP界面结合性能退化,削弱了材料整体承载能力。基于ABAQUS平台建立了CFRP的精细化有限元模型,通过VUMAT子程序定义材料本构关系,同时引入cohesive接触模拟纤维-基体界面的失效行为。仿真与试验最大误差在9.28%以内,验证了所建模型的有效性,为CFRP在酸热环境中的长期性能预测与可靠性设计提供了理论依据和技术支撑。

     

    Abstract: Carbon fiber reinforced resin matrix composites (CFRP) have been widely used in aerospace and other fields due to their advantages of high specific energy absorption, high specific strength and high specific modulus. However, CFRP is inevitably exposed to corrosive environments such as acid rain during long-term service. The lack of in-depth and systematic research on the performance evolution of CFRP under acid-heat coupling environment has become a key bottleneck restricting its reliable application in complex working conditions. In order to explore the degradation mechanism of mechanical properties of CFRP in acid-heat environment, the acid-heat aging test of CFRP was designed and the mechanical properties of materials were tested. The results showed that the acid-heat environment can cause the degradation of the matrix and the weakening of the fiber-matrix interface, which leads to the abnormal increase of the tensile strength of CFRP. The longitudinal and transverse tensile strength were increased by 93.85% and 7.14%, respectively, reflecting the load transfer mechanism dominated by carbon fiber. The longitudinal and transverse compressive strength decreased by 39.96% and 34.14%, respectively. The main reason is that acid corrosion leads to the degradation of CFRP interface bonding performance and weakens the overall bearing capacity of the material. A refined finite element model of CFRP was established using ABAQUS. The constitutive relationship of the material was defined by the VUMAT subroutine, and the cohesive contact was introduced to simulate the failure behavior of the fiber-matrix interface. The maximum error between simulation and test was within 9.28%, which verifies the validity of the model and provides theoretical basis and technical support for the long-term performance prediction and reliability design of CFRP in acid-heat environment.

     

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