掺杂改性的氧化锡电子传输层在钙钛矿太阳能电池中研究进展

Research progress on doping modified tin oxide electron transport layer in perovskite solar cells

  • 摘要: 自从制备出第一件钙钛矿太阳能电池器件以来,钙钛矿太阳能电池的光电转换效率已从3.8%飞跃至26.1%,是下一代商用太阳能电池的有力竞争者。近10年来,SnO2因其适宜的能带结构、较好的电子传输性能、简单的制备工艺以及良好的化学稳定性成为n-i-p型钙钛矿太阳能电池电子传输层材料的首选。虽然SnO2电子传输层优点众多,但还存在电子传输性能较差、传输层与钙钛矿层之间能级偏移、界面缺陷造成光生载流子大量损失以及成膜性能较差容易出现针孔等问题。鉴于此,本文总结了上述问题形成的主要原因,并通过金属离子掺杂、卤素离子掺杂、有机分子掺杂、纳米颗粒掺杂等不同溶液掺杂工艺研究结果的分析,阐明了不同掺杂工艺在解决溶液法SnO2薄膜缺陷以及在钙钛矿电池器件中应用的优点与缺点,并针对钙钛矿器件掺杂SnO2传输层性能优化做出展望。

     

    Abstract: Since the preparation of the first perovskite solar cell device, the photoelectric conversion efficiency of perovskite solar cells has jumped from 3.8% to 26.1%, making them a favorable competitor for the next generation of commercial solar cells. In the past decade, tin oxide has become the preferred electron transport layer material for n-i-p perovskite solar cells due to its suitable band structure, good electron transfer performance, simple preparation process, and good chemical stability. Although tin oxide electron transport layer has many advantages, there are still issues that need to be improved in terms of electron transport performance, such as energy level shift between the transport layer and the perovskite layer, interface defects causing significant loss of photo generated carriers, and poor film-forming performance that is prone to pinholes. In view of this, this article summarizes the main reasons for the formation of the above problems, and analyzes the research results of different solution doping processes such as metal ion doping, halogen ion doping, organic molecule doping, and nanoparticle doping. It elucidates the advantages and disadvantages of different doping processes in solving the defects of solution based tin oxide thin films and their applications in perovskite battery devices, and makes prospects for optimizing the performance of doped tin oxide transport layers in perovskite devices.

     

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