ZIF67-桉木纤维复合材料的制备及电磁屏蔽性能

Preparation and electromagnetic shielding properties of ZIF67-eucalyptus fiber composites

  • 摘要: 电磁污染问题日益凸显,开发高性能电磁屏蔽材料已成为一个重要的研究课题。对轻质、高强且应用广泛的纤维板进行功能化改性,已成为极具潜力的研究方向。但其缺乏自由电子与导电网络,无法有效吸收和转化电磁波。由此本研究在桉木纤维表面原位生长ZIF-67并结合一步热成型的策略,成功制备了具有高效电磁屏蔽性能的木质复合材料。ZIF上的金属离子可提供成键供体,与纤维中的羟基实现配位键,使得纤维板胶合强度为0.93 MPa。同时,ZIF-67的加入使功能纤维板的静曲强度从8.67 MPa提升至29.2 MPa。ZIF-67的Co2+具有介电损耗特性,可显著提升电磁屏蔽效能(EMI SE),EMI SE最高可以达24 dB。本研究创新了一种兼具电磁屏蔽性能与环保特性的功能纤维板,为健康家居材料的创新设计及功能应用提供了新路径。

     

    Abstract: The issue of electromagnetic pollution has become increasingly prominent, and the development of high-performance electromagnetic shielding materials has become an important research topic. The functionalization of lightweight, high-strength, and widely used fiberboards has become a highly promising research direction. However, their lack of free electrons and continuous conductive networks prevents them from effectively absorbing and converting electromagnetic waves. Therefore, in this study, ZIF-67 was in-situ grown on the surface of eucalyptus fiber and combined with one-step thermoforming strategy, a wood composite material with high electromagnetic shielding performance was successfully prepared.The metal ions in ZIF act as bonding donors and form coordination bonds with the hydroxyl groups in the fibers, resulting in a bonding strength of 0.93 MPa for the fiberboard. Meanwhile, the incorporation of ZIF-67 increased the modulus of rupture (MOR) of the functional fiberboard from 8.67 MPa to 29.2 MPa. The Co2+ ions in ZIF-67 exhibit dielectric loss characteristics, which significantly enhance the electromagnetic shielding effectiveness (EMI SE), reaching a maximum of 24 dB. This study introduces an innovative functional fiberboard that combines electromagnetic shielding performance with environmental sustainability, providing a new pathway for the innovative design and functional application of healthy building materials.

     

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