三维互穿网络结构MAX相陶瓷/镁复合材料制备与力学性能

Fabrication and mechanical properties of interpenetrating-phase Mg-based composites reinforced by MAX phase ceramics

  • 摘要: 通过选用微米和超细尺度的Ti3AlC2 MAX相陶瓷作为增强相,将陶瓷粉体在不同温度下热压烧结成多孔陶瓷骨架,进而将AZ91D镁合金熔体无压熔渗到骨架的孔隙中,制备了具有微观三维互穿网络结构的MAX相陶瓷/镁复合材料,表征了复合材料的相组成、微观结构与力学性能,考察了陶瓷相含量与特征尺寸对力学性能的影响。复合材料中金属和陶瓷两相各自保持连续且相互穿插,表现出超过1.96 GPa的高硬度和超过540 MPa的抗弯强度。随着陶瓷含量增加,复合材料的硬度提高,而抗弯强度和断裂韧性则同步降低,随着结构从微米细化到超细尺度,材料的硬度大幅提升,而断裂韧性降低。本工作有望为高强高硬镁基复合材料开发及其结构与性能优化提供新思路和指导。

     

    Abstract: By employing micrometer and ultrafine-scaled Ti3AlC2 MAX phase ceramics as reinforcement, porous ceramic scaffolds were manufactured via hot-press sintering of ceramic powders at varied temperatures. Subsequent pressureless infiltration of the pores of scaffolds with molten AZ91D Mg alloy resulted in the formation of interpenetrating-phase Mg-based composites reinforced by MAX phase ceramics. The phase composition, microstructure, and mechanical properties of the composites were characterized. The influence of ceramic phase content and characteristic dimensions on the mechanical properties of composites was investigated. Both the metal and ceramic phases were continuous and mutually interpenetrated with each other in the composites. The composites exhibited high hardness exceeding 1.96 GPa and flexural strength surpassing 540 MPa. An increase in ceramic content led to enhanced hardness, but with synchronous reduction in flexural strength and fracture toughness. The structural refinement of composites from micrometer to ultrafine scale yielded substantial improvements in hardness but decrease in fracture toughness. This study may offer new avenues and guidance for the exploitation of high-strength and high-hardness Mg-based composites as well as for the optimization of their structure and properties.

     

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