高性能热塑性树脂基复合材料的诱导结晶行为研究

Research on the induced crystallization behavior of high-performance thermoplastics resin-based composites

  • 摘要: 在热塑性树脂基复合材料中,优化界面性能对于提升复合材料的整体性能表现具有非常重要的作用。当碳纤维(CF)作为增强体与半结晶型的高性能热塑性树脂基体,如聚醚醚酮(PEEK)、聚芳醚酮(PAEK)或聚苯硫醚(PPS)等复合时,纤维与树脂界面上发生的诱导结晶现象,会对复合材料的界面性能产生显著影响。本文以高性能热塑性树脂基复合材料研究中诱导结晶问题为切入点,综述了该领域的研究进展。文章涵盖了从诱导结晶样品的制备方法到其最终性能变化的全过程,并分析了诱导结晶的类型及其影响因素,同时描述了高性能热塑性树脂中几种典型的横晶(TC)形态。此外,本文还着重探讨了TC结构对高性能热塑性树脂基复合材料界面性能的具体影响,并提出了当前该领域仍然存在的问题和面临的挑战。

     

    Abstract: In thermoplastic resin-based composites, optimizing interfacial properties is crucial for enhancing the overall characteristics of the composites. When carbon fibers (CFs) are employed as the reinforcement, combined with semi-crystalline high-performance thermoplastic resins such as polyetheretherketone (PEEK), polyaryletherketone (PAEK), or polyphenylene sulfide (PPS) as the matrix, the induced crystallization phenomenon at the fiber/resin interface significantly impacts the interfacial properties of the composite. Taking the issue of induced crystallization in the study of high-performance thermoplastic resin-based composites as the starting point, this article comprehensively reviews the research progress in this area. The article covers the entire process from the preparation methods of induced crystallization samples to their final performance changes, analyzes the classification and influencing factors of induced crystallization, and describes several typical transcrystallinity (TC) morphologies in high-performance thermoplastic resins. Additionally, this article focuses on discussing the specific impact of TC on the interfacial properties of high-performance thermoplastic resin-based composites, and proposes the existing problems and challenges in this field.

     

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