纤维面密度与树脂质量分数对CF/PEEK自动铺放原位成形质量的影响

Effect of fiber areal weight and resin mass fraction on the quality of CF/PEEK automated fiber placement in-situ moulding

  • 摘要: 纤维面密度与树脂质量分数通过影响层间传热与树脂流动行为,对激光辅助自动铺放热塑性复合材料原位固结质量具有重要影响。以碳纤维增强聚醚醚酮(Carbon fiber reinforced Polyetheretherketone, CF/PEEK)预浸料为研究对象,通过预埋热电偶监测铺放过程温度历史,并结合显微形貌观察、孔隙率定量分析、结晶行为表征及力学性能测试,系统研究了纤维面密度与树脂质量分数对原位成形层合板界面结合、孔隙演化及力学性能的影响规律。结果表明:纤维面密度增加会增大单层厚度并延长厚度方向传热路径,缩短层间有效熔融时间,导致界面结合性能下降,层合板孔隙率由0.20%增至2.48%,弯曲强度和层间剪切强度明显降低。提高树脂质量分数有利于界面树脂填充与气体排出,使孔隙率由1.35%降至0.13%;但树脂质量分数过高会因纤维承载比例降低及局部树脂富集而降低弯曲性能,同时结晶度由39.2%降至31.4%。实验结果表明,当纤维面密度为147 g/m2、树脂质量分数为29.9%时,CF/PEEK原位成形层合板获得最佳综合性能,层间剪切强度达到93.64 MPa,孔隙率为0.72%,低于航空结构件1%的孔隙率要求。

     

    Abstract: Fiber areal weight (FAW) and resin mass fraction are critical material parameters governing the quality of in-situ consolidation in laser-assisted automated fiber placement of thermoplastic composites, as they strongly influence interlaminar heat transfer and resin flow behaviour. In this study, carbon Fiber-reinforced polyether ether ketone (CF/PEEK) prepregs were investigated using embedded thermocouples to monitor the temperature history during placement. Combined with microstructural observation, quantitative porosity analysis, crystallisation characterisation and mechanical testing, the effects of FAW and resin mass fraction on interfacial bonding, pore evolution and mechanical performance of in-situ consolidated laminates were systematically examined. The results show that increasing FAW increases single-ply thickness and extends the heat transfer path in the thickness direction, thereby shortening the effective interlaminar melting time and weakening interfacial bonding. Consequently, laminate porosity increases from 0.20% to 2.48%, accompanied by significant reductions in both flexural strength and interlaminar shear strength. Increasing the resin mass fraction improves resin filling and gas evacuation at the interface, reducing porosity from 1.35% to 0.13%. However, further increases in resin mass fraction lead to reduced flexural performance due to the decreased Fiber load-bearing fraction and localised resin enrichment, while crystallinity decreases from 39.2% to 31.4%.Experimental results indicate that optimal performance is obtained at a fiber areal weight of 147 g/m2 and a resin mass fraction of 29.9%, where the CF/PEEK in-situ consolidated laminate achieves an interlaminar shear strength of 93.64 MPa and a porosity of 0.72%, well below the 1% porosity requirement for aerospace structural components.

     

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