等离子喷涂TiC-N i-M o 金属陶瓷涂层 成分对组织与性能影响的研究

EFFECT OF THE INGREDIENT OF PLASMA SPRAYING TiCNiMo CERMETS COATINGS ON THE MICROSTRUCTURE AND PROPERTIES

  • 摘要: 用XRD 和带能谱仪的SEM 等手段研究了两种不同成分配比的等离子喷涂TiC-Ni-Mo 金属陶瓷涂层的组织结构与性能; 提出在等离子喷涂的金属陶瓷涂层中, 硬质相与粘结相之间存 在通过Mo 扩散固溶实现的扩散结合机制, 由此而在TiC 颗粒周围形成(Ti、Mo )C 固溶体包复结 构; 适当控制这种包覆结构的厚度可以增加硬质相与粘结相之间的结合力和涂层的结合强度。研 究结果表明, 喷涂混合粉粒中,Ni 与TiC 的重量配比为1∶1 时比5∶3 时所形成涂层的硬度和结 合强度更高。

     

    Abstract: The microstructure and properties of two plasma spraying TiCNiMo cermets coatings with different ingredient ratios are studied by XRD, SEM and energy spectrometer. It is presented that in the diffusion bonding mechanism, between hard phase and bonding phase there was a way of Mos diffusion and solid solutizing; and so the (Ti,Mo)C solid clad structure around TiC grain is formed; the bond between hard phase and bonding phase and also the bonding strength of the coatings can be strengthened by controlling properly the thickness of the clad structure.The results show that for spraying compound particles, when the ingredient ratio (wt%) of Ni and TiC is 11, the hardness and bonding strength of the coating are higher than those of the coating of which the ingredient ratio of Ni and TiC is 53.

     

/

返回文章
返回