稀土改性二氧化钛电流变液的剪切强度随温度变化关系

TEMPERATURE EFFECTS OF SHEAR STRESS OF THE ELECTRORHEOLOGICAL FLUIDS MADE OF MODIFIED TITANIA DOPED WITH RARE EARTH

  • 摘要: 用溶胶-凝胶法制备了系列锐钛矿型掺杂稀土元素二氧化钛粉粒,在干态下对其所配制的电流变液进行了力学性能测试及其温度效应研究。结果表明,掺杂后的电流变液性能远优于同条件下所制纯二氧化钛电流变液。温度效应明显优化,在10 ℃~100 ℃均有较强的电流变活性,使用温度范围比纯二氧化钛电流变液大幅度加宽,80℃剪切应力达到最大。材料中的RE/Ti摩尔比对电流变效应影响显著,不同温度下RE/Ti=0.07~0.11之间电流变液呈现最佳的电流变效应,RE/Ti摩尔比引起电流变液介电性质的改变是电流变效应增强和不同的起因。

     

    Abstract: The electrorheological(ER) behavior of the water-free suspensions made of modified titania(TiO2) doped with rare earth(RE), synthesized by means of Sol-gel technique, in polydimetyl-silicone oil has been investigated under a DC field. In particular, the temperature dependence of the induced shear stress of ER suspensions has been studied carefully. In the results, it can be found that pure titania based ER fluids have almost no ER effects, but modified titania based ER fluids have a strong ER effect. The strong ER effect can be kept in the range from 10 ℃ to 100 ℃ in modified titania based ER fluids, the induced shear stress increases with temperature and reaches the maximum at 80℃. But the induced shear stress of pure titania based ER fluids reaches the maximum at 40 ℃, and then declines quickly. In addition, the remarkable characteristic is that the induced shear stress has a dependence on RE/Ti mole ratio and reaches a higher ER effect when RE/Ti mole ratio is about 0.07~0.11 at different temperatures. This can be explained by the dependence of dielectric properties of ER fluids on RE/Ti mole ratio.

     

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