KINETIC ANALYSIS ON Al-TiO2 SYSTEM BY XD SYNTHESIS TECHNOLOGY
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摘要: 通过XD(Exothermic Dispersion)法原位反应生成Al2O3与Al3Ti增强的铝基复合材料,对反应过程动力学机理进行了探讨。结果表明Al/TiO2经充分混合、挤压成坯后,在真空炉中以一定的升温速率加热至800℃左右时发生剧烈的化学反应。SEM、XRD及能谱分析可知:生成物Al2O3呈等轴颗粒状,Al3Ti呈棒状,并进一步说明了升温速率、铝含量、压坯的预紧实度等因素对反应结果的影响。Abstract: Al2O3, Al3Ti/Al in situ aluminum matrix composite material was prepared by means of XD(exothermic dispersion)synthesis technique. Its kinetic mechanism was also discussed. The results showed that the Al-TiO2system can react in a very short time. The reaction was propagated in combustion wave. It was also shown that aluminum initially reacted with TiO2 to form Al2O3 and reduced Ti. The Al2O3 and Al3Ti took the shape of equal axial particle and block respectively. A certain heating rate and content of aluminum are needed, if thermal explosion occurs commonly in the Al-TiO2 system. The bulk shrinkage will be higher with lower heating rate, higher aluminum content and lower green density.
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Key words:
- in situ chemical reaction /
- kinetics /
- combustion wave /
- aluminum matrix composites
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