纳米改性金属陶瓷的组织和力学性能

MICROSTRUCTURE AND MECHANICAL PROPERTIES OF NANO MODIFIED CERMETS

  • 摘要: 讨论了纳米TiN改性TiC基金属陶瓷(纳米改性金属陶瓷)的组织与力学性能。结果表明,金属陶瓷组织仍为两相结构(陶瓷相+金属相),其中粗大的陶瓷相为芯/壳结构,即Ti(C,N)芯外包覆有一层硬质相(Ti,Mo,W)(C,N)(即"SS"相)。TEM观察显示,纳米TiN主要在两相或三相晶界上分布。随纳米TiN的增加,纳米改性金属陶瓷的组织明显细化;组织的细化与纳米TiN在TiC/TiC晶界的分布阻止了TiC晶粒的长大有关。抗弯测试表明,抗弯强度在添加8 wt%纳米TiN时达到最大值;抗弯断口显示沿晶断裂为主要的断裂模式。

     

    Abstract: The microstructure and mechanical properties of nano TiN modified TiC based cermets(nano modified cermets) have been discussed. Results reveal that the microstructure still consists of a ceramic phase and a metal phase, and the coarse ceramic phase in the microstructure exhibits a core/shell structure, i.e. the coarse ceramic phase generally consists of a Ti(C,N) core surrounded by a shell ("SS" phase). TEM observations show that nano TiN grains are generally distributed at the interfaces of two phases or three phases. The microstructure of nano modified cermets becomes finer with increasing the amount of nano TiN addition, and the fining effect can be related to the distribution of nano TiN at the interfaces of TiC/TiC and the inhibition of the growth of TiC grains. Bending tests show that the bending strength will reach a maximum value when the amount of nano TiN reaches 8wt%. Fracture photograph shows that intergranular fracture is the main failure mode.

     

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