炭黑改性对炭黑/高密度聚乙烯体系电性能稳定性的影响
Effect of carbon black modification on the electrical reproducibility behavior of CB/HDPE composites
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摘要: 采用熔体共混法制备了炭黑(CB)/高密度聚乙烯(HDPE)导电复合材料。研究了硝酸氧化对CB/HDPE导电复合材料正温度系数(PTC)、负温度系数(NTC)效应和电性能稳定性的影响。结果表明,填充氧化炭黑(CB-O)提高了CB-O/HDPE体系的电性能稳定性和PTC强度,部分消除或降低了复合材料的NTC效应。而CB-O/HDPE体系的室温电阻率比CB/HDPE体系只增加了0.3个数量级,但比经过交联处理的CB/HDPE(CB/crosslinked-HDPE)体系降低了1个数量级。CB-O/HDPE复合材料性能的改善主要是由于CB经氧化后,表面羧基、羟基等极性基团含量增加,抑制了CB粒子高温时的自团聚作用,减弱了体系的NTC效应;同时CB表面微晶晶界处导电性较差区域的减少,提高了CB的导电性,,并且CB-O表面大量孔洞和裂缝的形成,增强了CB-O与HDPE的物理吸附作用,提高了复合材料的电性能稳定性。Abstract: The carbon black (CB) or oxidative carbon black (CB-O) filled high-density polyethylene composites were prepared by melting blending. The influence of CB oxidation on the positive temperature coefficient (PTC) behavior,negative temperature coefficient (NTC) behavior and the electrical reproducibility of CB/HDPE and CB-O/HDPE composites were studied. It is shown that the NTC effect is decreased or even eliminated,the electrical reproducibility is improved and the PTC intensity is enhanced by CB oxidation. It is also revealed that the room temperature resistivity of CB-O/HDPE is increased by only 0.3 order compared with CB/HDPE,but is lower by one order than that of crosslinked CB/HDPE. The results are due to the increase of the polarity on the surface of CB-O,which is induced by the increase of the carboxyl and hydroxyl. Thus the agglomeration of CB-O at high temperature is restricted and the NTC effect of the composites is decreased. On the other hand,the reduction of the poor electrical conductive regions at boundaries of the crystallites on the surface of CB improves the electrical conductivity of the composites and the strong physical adsorption interaction between CB-O particles and HDPE improves the electrical reproducibility of the composites.