生物质多孔碳基硅碳负极材料预处理研究综述

A review on the pre-treatment of biomass-derived porous carbon-based silicon-carbon anode materials

  • 摘要: 生物质多孔碳凭借其原料成本低廉、高碳组分含量及天然分级孔隙结构等特性,在锂离子电池硅碳负极材料领域展现出显著应用潜力,其三维纤维网络可有效提升电极导电性并缓解硅相体积膨胀效应。然而,生物质直接碳化制备的多孔碳存在孔隙结构分布不均、杂质残留显著等问题,亟须通过预处理工艺优化其微观形貌与组分构成,从而获得电化学性能优异的碳基质材料。本文聚焦生物质多孔碳基硅碳负极材料制备体系,系统综述了生物质预处理工艺的作用和机理,以及化学法、物理法和生物法等三种生物质多孔碳基硅碳负极材料预处理研究进展,为后续研究者在生物质多孔碳预处理工艺的选择和应用上提供参考。

     

    Abstract: Biomass-derived porous carbon, with its low raw material cost, high carbon content, and natural hierarchical porous structure, has shown significant application potential in the field of silicon-carbon anode materials for lithium-ion batteries. Its three-dimensional fibrous network can effectively enhance electrode conductivity and mitigate the volume expansion effect of silicon phases. However, porous carbon prepared by direct carbonization of biomass suffers from uneven pore structure distribution and significant impurity residues. It is imperative to optimize its microstructure and composition through pre-treatment processes to obtain carbon matrix materials with excellent electrochemical performance. This paper focuses on the preparation system of biomass porous carbon-based silicon-carbon anode materials, systematically reviews the role and mechanism of biomass pre-treatment processes, and provides an overview of the research progress on pre-treatment of biomass porous carbon-based silicon-carbon anode materials using chemical, physical, and biological methods, offering references for future researchers in the selection and application of pre-treatment processes for biomass porous carbon.

     

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