原位聚合法制备纳米凹凸棒土/聚乳酸复合材料
Preparation of nano-attapulgite/polylactide composites by in situ polymerization
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摘要: 将凹凸棒土(AT)进行提纯和有机改性后, 采用原位聚合法制备了OAT质量分数为1%、 3%、 5%的纳米凹凸棒土/聚乳酸复合材料(OAT/PLA-x)。采用红外、 扫描电镜、 X射线衍射等对复合材料进行了表征, SEM结果表明, 凹凸棒土粒子在复合材料中实现了均匀稳定分散。复合材料的力学性能和综合热性能测试表明: OAT/PLA-3复合材料的拉伸强度、 弹性模量分别比纯PLA增加98.6%和130.0%; 复合材料的热稳定性明显提高。同时, 复合材料的溶液降解速率也明显加快。Abstract: Organic---attapulgite (OAT) was obtained by pretreating attapulgite, then the nano---OAT/polyactide (PLA)-x ( x=1wt%、 3wt%、 5wt%) composites were prepared respectively by in situ polymerization. The composites were characterized by infrared absorption spectroscopy (IR), scanning electronic microscope (SEM) and X-Ray diffraction (XRD). SEM results show equably uniform dispersion and good interfacial compatibility between PLA and OAT. The mechanical capability and thermal analysis (TGA & DSC) of the composies were measured. Compared with the pure PLA, the tensile strength and elastic modulus of the OAT/PLA3 are improved by 98.6% and 130.0% respectively. The thermal stability of composites is markedly improved. It also shows that the degradation velocity of OAT/PLA-x is obviously speeded up.