水系锌离子电池锌负极界面与结构改性策略研究进展

Progress in Interfacial and Structural Modification Strategies for Zinc Anodes in Aqueous Zinc-ion Batteries

  • 摘要: 水系锌离子电池凭借高安全性、资源丰富、成本低廉及锌负极高理论容量等优势,成为大规模储能领域极具前景的候选体系。然而,锌金属负极锌枝晶生长、析氢反应、腐蚀及表面钝化等一系列副反应,严重制约了电池的循环寿命与商业化进程。本文系统梳理了近年来锌负极改性的主要策略,重点围绕界面调控、结构设计、电解液优化与隔膜修饰四个方向,深入阐述了各改性策略的作用机制与协同效应,并对不同改性方法的优势与局限进行评述。最后,对未来长寿命、高安全性与高可逆性锌负极的研究路径进行了展望,为推动高性能水系锌离子电池的科学研究及商业化进程提供理论参考。

     

    Abstract: Aqueous zinc-ion batteries (AZIBs) have emerged as a highly promising candidate for large-scale energy storage due to their high safety, resource abundance, low cost, and the high theoretical capacity of zinc anodes. However, the development of AZIBs is significantly constrained by a series of side reactions at the zinc metal anode, including zinc dendrite growth, hydrogen evolution, corrosion, and surface passivation, which severely hinder cycling life and commercialization. This review systematically summarizes the main modification strategies for zinc anodes developed in recent years, focusing on four key approaches: interface regulation, structural design, electrolyte optimization, and separator modification. It elaborates on the mechanisms and synergistic effects of various modification strategies and provides a critical assessment of the advantages and limitations of different methods. Finally, future research directions for achieving zinc anodes with long lifespan, high safety, and high reversibility are outlined, aiming to provide theoretical insights for advancing both the scientific research and commercialization of high-performance aqueous zinc-ion batteries.

     

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