钛酸钾晶须改性MC尼龙的吸湿行为及摩擦学特性
Moisture absorbing ability and tribology capability of potassium titanate whiskers reinforced MC nylon
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摘要: 机车心盘衬垫的性能易受湿度的影响而很不稳定,为了改善吸湿性对机车心盘衬垫性能的影响,在提高制品的韧性和强度的同时,获取高且稳定的摩擦系数,通过碱催化阴离子聚合反应制备了钛酸钾晶须/MC尼龙复合材料,并经过水浴处理。利用MM2000型摩擦磨损实验机测试了在干摩擦条件下吸湿性对钛酸钾晶须/MC尼龙复合材料摩擦学性能的影响。实验发现,未水浴处理试样的摩擦系数易受吸湿性的影响而不稳定,水浴处理试样的摩擦系数则能较快地稳定。纯尼龙以粘着磨损为主,钛酸钾晶须的加入大大降低了粘着磨损程度。晶须填充试样的总质量磨损率小于纯尼龙试样,但吸湿性对材料磨损特性的影响并不明显。晶须填充MC尼龙在水浴处理的条件下能明显改善吸湿性对MC尼龙摩擦学性能的影响。Abstract: PTW (Potassium titanate whiskers) reinforced monomer casting(MC)nylon composites were prepared by anionic polymerization of caprolactam for improving the ability of train plates’ gasket affected by absorbing moisture to get a high and steady friction coefficient beside better toughness and intensity,and treated by boiled water. The tribological properties of the composites were investigated by a ring-blank wear tester under dry condition. Compared with the samples treated by boiled water,the friction coefficient of the untreated sample becomes instable because of the moisture absorbing ability,while the treated one could get stability in a short time. The main wear mechanism of the pure nylon is adhesive,and the PTW reinforced MC nylon reduces the adhesive wear obviously. The total mass wear ratio of the pure sample is higher than that of the reinforced one. The moisture absorbing ability cannot affect the wear mechanism obviously. The PTW reinforced monomer casting nylon treated by boiled water could improve the tribological capability.