超重力下燃烧合成TiB2-TiC共晶复合陶瓷

TiB2-TiC eutectic composite ceramics prepared by combustion synthesis under high gravity

  • 摘要: 采用超重力下燃烧合成技术,制备出TiB2-TiC共晶复合陶瓷。XRD、SEM与EDS结果表明,复合陶瓷主要由大量细小的TiB 2片晶均匀分布于TiC基体上的共晶组织构成,而富钛ε碳化物(Ti , Cr)C1-x则断续分布于TiC基体间,同时在基体中还孤立分布着少量的、形态不规则的α-Al2O3晶粒或Al2O3-ZrO2共晶团组织。高温化学反应使所有产物均呈液态,且超重力的引入诱发熔体内部Stocks流,从而获得液态Ti-Cr-C-B与液态氧化物的分层熔体,液态Ti-Cr-C-B在远离平衡态下发生共晶反应生成TiB 2 2TiC共晶复合陶瓷。性能测试表明,随着B4C + Ti + C在燃烧体系中质量分数增加,TiB2-TiC共晶复合陶瓷相对密度和断裂韧性变化不大 , 分别为97 %~99 %与6. 5~7. 1 MPa·m1/2,而维氏硬度与弯曲强度则逐渐增加,最高可达28. 6 GPa与615 MPa。

     

    Abstract: TiB2-TiC eutectic composite ceramics were prepared by combustion synthesis under high gravity. XRD ,SEM and EDS results show that TiB2-TiC composites are mainly composed of the eutectic microst ructures of TiC matrix, in which a large number of the fine TiB2 platelet grains are dispersed uniformly ; meanwhile, at the boundaries of the eutectic microst ructures there discontinuously disperse the ε-carbides with the enrichment of Tiatoms, and a few of isolated , irregular α-Al2O3 grains and Al2O3-ZrO2 colonies are also observed. Because high-temperature chemical reaction results in the full-liquid products, and the introduction of high gravity induces the Stocks flow in the melts, leading to the formation of layered melt s consisting of liquid Ti-Cr-C-B and liquid oxides, it is considered that TiB2-TiC composites grow through eutectic t ransformation far away f rom the equilibrium state.The results of properties indicate that with increasing mass fraction of B4C + Ti + C in combustion systems , the relative density and f racture toughness of TiB2-TiC composites are all among 97 %~99 % and 6. 5 ~7. 1 MPa·m1/2 , respectively, and the Vickers hardness and flexural strength are increased gradually to the maximum values of 28. 6 GPa and 615 MPa, respectively.

     

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