Nb0.74CoCrFeNi2高熵钎料钎焊陶瓷基复合材料和金属的高温连接性能

High-temperature joining properties of Nb0.74CoCrFeNi2 high-entropy filler for brazing ceramic matrix composites and metals

  • 摘要: 陶瓷基复合材料和金属材料在高温下的连接性能至关重要。本文采用Nb0.74CoCrFeNi2高熵粉末钎料对C/SiC陶瓷基复合材料与GH4169金属进行钎焊连接,揭示了钎焊接头微观组织形貌的演化过程及形成机制,探究了钎焊接头的室温、800℃和1000℃高温下的连接性能。结果显示钎焊接头典型结构为:Cr23C6+(Cr,Fe)23C6/(Cr,Fe)3C2+Ni2Si+NbC/FCC+(Cr,Fe)3C2+Ni2Si,C/SiC陶瓷基复合材料侧界面上随着反应的进行,Cr元素被逐渐消耗,形成了独特的梯度界面结构。随着钎焊温度升高或保温时间延长,焊缝内部缺陷逐渐消失,但脆性界面反应层厚度急剧增加,导致接头室温连接强度呈现先升高后降低的趋势,钎焊接头连接强度最高为188.1 MPa,800℃高温连接强度高达107.7 MPa,1000℃高温连接强度依然保持57.6 MPa。高连接强度源于钎料中Ni元素向C/SiC复合材料侧扩散,使纤维束丝与基体形成了较强的界面结合。

     

    Abstract: Nb0.74CoCrFeNi2 high-entropy powder filler was used to braze C/SiC composites andGH4169, and the effects of brazing temperature and holding time on the microstructure and shear strength of the joints were systematically investigated to reveal the formation mechanism of the joints. It was found that the typical structure of joint is Cr23C6+(Cr,Fe)23C6/(Cr,Fe)3C2+Ni2Si+NbC/FCC+(Cr,Fe)3C2+Ni2Si. With the reaction progressing on the side interface of the composite material, the Cr element was gradually consumed, forming a unique gradient interfacial structure, which is conducive to the relief of residual stresses in the joint. With the increase of brazing temperature or the prolongation of holding time, the internal defects of the joints gradually disappeared, but the thickness of the brittle interfacial reaction layer increased sharply, resulting in the joint shear strength showing a tendency of first increasing and then decreasing. When the brazing temperature is 1260 ℃ and the holding time is 25 min, the shear strength of the brazed joint is up to 188.1 MPa, and high-temperature shear strength up to 107.7 MPa at 800℃, and still 57.6 MPa at 1000℃. The high shear strength originates from the diffusion of Ni element from the brazing material into the SiC matrix of the composite material, which forms a strong interfacial bond between the fiber bundles and the matrix.

     

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