Influence of the dispersion of carbon black on the resistivity and electromechanical properties of carbon black filled epoxy matrix conductive composites
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摘要: 通过实验研究了搅拌时间和炭黑表面改性对炭黑/环氧树脂导电复合材料电阻率和力电性能的影响。实验结果表明,随着搅拌时间的延长,炭黑在环氧树脂中的分散性提高,炭黑在环氧树脂中形成的一些导电链被破坏,从而导致复合材料的电阻率提高,电阻率变异系数减小及同批试件的电阻随应变的变化率趋于一致。但进一步延长搅拌时间并不能提高分散性,炭黑仍是以较大聚附体的形式存在。炭黑经偶联剂表面改性后,在环氧树脂中的分散性得到进一步的提高。改性后炭黑以小的聚附体甚至单颗粒的形式分散于环氧中,从而减小了复合材料中分布于炭黑颗粒间环氧树脂间隙的宽度,使复合材料的电阻率和电阻随应变的变化率减小。Abstract: The influences of stirring time and surface modification of carbon black (CB) on the resistivity and electromechanical properties of CB filled epoxy matrix composites were experimentally studied. The test results indicate that the dispersion of CB in the epoxy can be improved with the increase of stirring time,which is at tributed to the fact that some conductive chains in the epoxy formed by CB are broken up when the stirring time increases and thus the resistivity of composites is improved. Consequently,the variation coefficient of resistivity and the fractional change of resistance versus strain between the specimens prepared at the same time are decreased. But the dispersion of CB in epoxy cannot be further improved when the stirring time becomes longer and the CB particles dispersed in epoxy are still in formation of big agglomerations. The dispersion of CB particles in epoxy is improved further after the surface of CB particles is modified by silane coupling agent. The CB particles modified by silane coupling agent are dispersed in epoxy in formation of little agglomerations and even single particles,so the epoxy gaps between CB agglomerations become thinner and the resistivity and the fractional change of resistance versus strain of the composites decrease accordingly.
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Key words:
- carbon black /
- silane coupling agent /
- resistivity /
- electromechanical property /
- composites
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