PET-MFIAA/ PP原位成纤复合材料的形态结构及力学性能
Morphology and mechanical properties of PET-MFIAA/ PP in situ fiberized composites
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摘要: 用钉挂预埋多功能界面活化剂(MFIAA)的PET(PET-MFIAA)与PP共混 - 挤出 - 拉伸,制备了PET-MFIAA/PP原位成纤复合材料,采用扫描电镜、偏光显微镜观察和力学性能测定的方法,研究了PET-MFIAA/PP的PET微纤形态、试样断面形态及力学性能,并与PET/PP、MFIAA/PET/PP两种原位成纤复合材料进行对比。结果表明: PET-MFIAA/PP PET微纤与PP基体间具有强的相互作用,PET微纤呈粗细不均匀、凹凸不平的异形形态及柔性界面等结构特征,形成了强的界面结合,其刚性、韧性均比纯 PP明显提高,含7.00% MFIAA的PET-MFIAA/PP复合材料的拉伸屈服应力、弯曲弹性模量和悬臂梁缺口冲击强度分别达到了纯PP的1.04倍、1.23倍和1.79倍。Abstract: Using polypropylene (PP) and poly ( ethylene terephthalate) (PET) with the multifunction interlayer active agent riveting-embedded (PET-MFIAA),the PET-MFIAA/PP in situ fiberized composites were prepared by blending-extrusion-drawing. By means of scanning electronic microscope (SEM),polarized microscope (PLM) and mechanical properties measuring,the PET microfibril morphology,fracture surface morphology of samples and the mechanical properties of the PET-MFIAA/PP were studied and contrasted with two other kinds of in situ fiberized composites of PET/PP and MFIAA/PET/PP. The results show that there is strong interfacial adhesion in the PET-MFIAA/PP in situ fiberized composites,which has structure characteristics of powerful interaction between PET microfibril and PP matrix,PET microfibril presenting profiled morphology of diameter variation and concave and convex surface,flexible interlayer,etc. Both rigidity and toughness of PET-MFIAA/PP are apparently higher than those of the pure PP. The tensile yield strength,flexural modulus and notched izod impact strength of the PET-MFIAA/PP composite containing 7. 00 % MFIAA are raised to 1.04 times,1.23 times and 1.79 times as the pure PP respectively.