Structures and electro-magnetic and optical properties of the Co doped ATO composite thin films
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摘要: 以低成本的无机盐 SnCl2·2H2O、SbCl3和Co(NO3)2·9H2O 为原料,采用溶胶-凝胶法与浸渍提拉技术成功地制备出Co掺杂的ATO(Sb掺杂SnO2)复合薄膜。利用XRD、SEM、四探针电阻仪、紫外-可见光分光光度计及振动样品磁强计(VSM)等测试方法对Co/ATO复合薄膜的结构与物性进行了表征与评价。结果表明:少量的Co 掺杂ATO复合薄膜仍保持四方金红石结构,复合薄膜中的晶粒分布均匀,其晶粒尺寸分布为4~7 nm;随着Co含量的增加,Co/ATO复合薄膜的电阻率呈现出先降低后提高,且当Co含量为0.5 mol %时,Co/ ATO复合薄膜的电阻率最低为5. 6×10- 3Ω·cm;在400~700 nm可见光范围内,平均透过率达到90 %以上,其光学带隙在3.9~4.0eV之间,且随着Co含量的增加,可见光透过率和光学带隙呈下降趋势;Co含量为3.0 mol%的ATO复合薄膜具有室温铁磁性,其矫顽力约为100Oe,磁性根源主要归结为磁性原子与基体载流子相互作用的结果。
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关键词:
- 溶胶-凝胶法 /
- Co/ATO复合薄膜 /
- 结构表征 /
- 电磁光特性
Abstract: The Co doped ATO (Antimony (Sb) doped tin oxide (SnO2) composite films were successfully synthesized by using sol-gel combined with dip-coating methods and originating from the primary materials of SnCl2·2H2O,SbCl3 and Co(NO3)2· 9H2O. The structures and properties of Co/ATO composite films were characterized by X-ray diffraction (XRD),scanning electron microscope (SEM),four-probe method,ultraviolet visible near-infrared spectrophotometer and vibrating sample magnetometer (VSM). The results indicate that a tetragonal rutile structure is retained by a little Co doped ATO,and the nano-particles are well distributed in the thin films and their size can be controlled in the range of 4~7 nm. With increasing the Co content,the resistivity of the composite films decreases and then increases,and it presents a very low value at 0.5 mol% Co. In the range of 400~700 nm visible region,the transmit tance values are up to 90 %,also the transmit tance in the visible region and the optical band gap trends to decrease with increasing the Co content. The room temperature ferromagnetism of the composite film has a coercive force of about 100 Oe when the Co-doped is 3.0 mol%,and it is mainly originated from the interaction of magnetic atoms and the body carrying ions.
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