弹性体修饰纳米SiO2粒子改性PBT

PBT matrix composites with elastomer-modified nano-SiO2 particles

  • 摘要: 选用乙烯-丙烯酸酯-甲基丙烯酸缩水甘油酯(E-MA-GMA)三元共聚物对纳米SiO2表面进行修饰包覆改性,考察改性后纳米SiO2在聚对苯二甲酸丁二醇酯(PBT)基体中的分散情况及对PBT复合材料力学性能的影响。FTIR、TEM、SEM结果表明,E-MA-GMA的环氧基团与纳米SiO2的—OH 基团发生反应,破坏了SiO2的链状团聚结构,降低了纳米粒子间氢键等作用力。质量分数为10%~20% E-MA-GMA 改性的纳米SiO2在PBT基体中的分散性及其与基体的相容性均得到明显改善,从而提高了PBT基复合材料的弯曲和拉伸性能。与纯PBT相比,SiO2/PBT复合材料的拉伸强度提高了9%,而弯曲强度和模量分别提高了14%和20%。

     

    Abstract: Nano-SiO2 was firstly modified by coating with ethylene-methyl acrylate-glycidyl methacrylate (E-MA-GMA) elastomer through the direct solvent process,and the dispersion of nano-SiO2 in PBT and the effects of modified nano-SiO2 on the properties of PBT were investigated. FTIR,TEM and SEM results indicate that the epoxy group of E-MA-GMA can react with the hydroxyl groups of the silica surface to destroy the aggregation of SiO2 and reduce the interactions between the nano-SiO2 particles;SEM results show that the mass ratios of 10%~20% E-MA-GMA can improve the dispersion of nano-SiO2 in PBT and the interfacial adhesion between the two phases,and thus the flexural properties and tensile strength of nano-SiO2/PBT composite are increased. The incorporation of E-MA-GMA modified SiO2 particles increases the tensile strength,flexural strength and flexural modulus by 9%,14% and 20% higher than those of pure PBT respectively.

     

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