纳米SiC晶须和SiC颗粒混合增韧ZrB2陶瓷性能

Properties of ZrB2 ceramics reinforced by SiC nanowhiskers and SiC particles

  • 摘要: 分别采用纳米SiC晶须(SiCW)、SiC颗粒(SiCP)及SiCW与SiCP共同增韧ZrB2陶瓷,在1950℃、20 MPa压力、氩气气氛下热压烧结制备了致密的SiC/ZrB2陶瓷材料。研究了SiCW和SiCP的添加量对于SiC/ZrB2陶瓷材料的显微结构、力学性能的影响,并分析了SiCW和SiCP对ZrB2陶瓷力学性能影响的协同作用和增韧机制。结果表明:含15 vol% SiCW 的复合材料的韧性达到8.08 MPa·m1/2,含15 vol% SiCP的复合材料的韧性达到8.515MPa·m1/2,共同添加15 vol% SiCW和15 vol%SiCP的复合材料的韧性最高达到9.03 MPa·m1/2。SiC/ZrB2复合材料强度和韧性提高的原因在于SiCW和SiCP抑制ZrB2晶粒长大,促进ZrB2的致密化,此外,SiCW和SiCP的协同作用也有助于材料韧性的提高。

     

    Abstract: SiC/ZrB2 composites reinforced by SiC nanowhiskers (SiCW ) and SiC particles (SiCP) were prepared by a hot-pressing process at 1950℃ under 20 MPa in a flow argon atmosphere. The effects of SiCW and SiCP on microstructures,mechanical properties of SiC/ZrB2 composites were investigated. The results showed that the fracture toughnesses of SiC/ZrB2 composites with 15 vol% of SiC Wand with 15 vol% of  SiCP were 8.08 MPa· m1/2 and 8.515 MPa·m1/2,respectively. The fracture toughness of the SiC/ZrB-composites with both 15 vol% of SiCW and 15 vol% of SiCP reached 9.03 MPa·m1/2. SiCW and SiCP effectively improved the densification of SiC/ZrB2 composites,and limited the coarsening of ZrB2 grains,which was in favor of improving the bending strength and fracture toughness of the SiC/ZrB2 composites. Furthermore,the synergistic effect of SiCW and SiCP favored the increase of the toughness.

     

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