葡萄糖酸钠调控绿色低碳超细水泥注浆材料性能的微观机制及宏观响应

Microscopic mechanism and macroscopic response of sodium gluconate in regulating the performance of green and low-carbon ultra-fine cement grouting materials

  • 摘要: 为解决传统硫铝酸盐水泥(SAC)浆液凝结速度快、流动度不足、可注性差且固废利用率低问题,满足深部巷道围岩绿色注浆加固工程需求,通过超细加工处理SAC熟料、煅烧改性工业副产脱硫石膏和生石灰原料,利用葡萄糖酸钠作缓凝剂,研发一种兼具高流态与可控凝结时间的绿色低碳超细水泥注浆材料。采用不同表征手段探究葡萄糖酸钠掺量对超细硫铝酸盐水泥注浆材料(USCGM)流动度、凝结时间、体积膨胀性及力学强度的影响规律,并基于砂岩骨料注浆固结试验评价USCGM胶结碎石的力学承载性能。结果表明,USCGM浆液的凝结时间、流动度与葡萄糖酸钠掺量呈正相关关联,即二者随葡萄糖酸钠掺量增加不断增大,而结石体体积膨胀率、抗压强度随葡萄糖酸钠掺量呈先增大后减小趋势。0.5%缓凝剂下USCGM的综合性能达到最佳,初、终凝时间比空白对照组延长27.51%、59.23%,流动度提升10.81%,早期抗压强度(8 h、1 d)虽略有下降,但3 d~28 d抗压强度明显提升3.3%~5.83%,实现工作性能与后期力学强度发展的综合改善。XRD、SEM、FTIR与水化热表征表明,适宜葡萄糖酸钠添加有助于延缓早期AFt生成,调控AFt晶体形貌,优化结石体孔隙结构,发挥“化学络合缓凝-物理吸附阻水-晶体调控增强”三重耦合作用。注浆加固试验表明,0.5%葡萄糖酸钠改性USCGM砂岩胶结体的峰值荷载、对应滑移量比照组提升14.21%、18.5%,显示增强的力学承载性能和塑性变形能力。

     

    Abstract: To address the issues of rapid setting, insufficient fluidity, poor injectability and low utilization of solid waste in traditional sulphoaluminate cement (SAC) slurry, and to meet the requirements of deep roadway surrounding rock green grouting reinforcement engineering, a green and low-carbon ultrafine cement grouting material with high fluidity and controllable setting time was developed by ultrafine processing of SAC clinker, calcination modification of industrial by-product desulfurization gypsum and quicklime, and using sodium gluconate as a retarder. The effects of sodium gluconate dosage on the fluidity, setting time, volume expansion and mechanical strength of ultrafine sulphoaluminate cement grouting material (USCGM) were investigated by different characterization methods. The mechanical bearing performance of USCGM cemented crushed stone was evaluated based on sandstone aggregate grouting consolidation tests. The results show that the setting time and fluidity of USCGM slurry are positively correlated with the dosage of sodium gluconate. They increase with the increase of sodium gluconate dosage, while the volume expansion rate and compressive strength of the hardened samples increase first and then decrease. The comprehensive performance of USCGM is the best at 0.5% retarder, with the initial and final setting times of the blank control group extended by 27.51% and 59.23% respectively, and the fluidity increased by 10.81%. Although the early compressive strength (8 h, 1 d) slightly decrease, the compressive strength from 3 d to 28 d increase by 3.3% to 5.83%, achieving a comprehensive improvement in working performance and later mechanical strength development. XRD, SEM, FTIR and hydration heat characterization show that appropriate sodium gluconate helps to delay the early formation of AFt, regulates the morphology of AFt crystals, and optimizes the pore structure of the stone. It plays a triple coupling role of "chemical complexation retardation-physical adsorption water blocking- crystal regulation strengthening". The grouting reinforcement test shows that the peak load and corresponding slip of 0.5% sodium gluconate modified USCGM sandstone cemented specimen are increased by 14.21% and 18.5% respectively compared with the control group, indicating enhanced mechanical bearing capacity and plastic deformation ability.

     

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