木棉/ES多孔材料增强聚丙烯酸钠水凝胶制备及其溶胀动力学分析

Preparation of Kapok/ES Porous Material Reinforced Sodium Polyacrylate Hydrogel and Analysis of Its Swelling Kinetics

  • 摘要: 以木棉纤维和聚对苯二甲酸乙二醇酯纤维(ES)为原料,通过冷冻干燥工艺与热风粘合工艺制备具有良好力学性能的多孔材料,并将其作为骨架来增强聚丙烯酸钠水凝胶,并研究其微观形貌、力学性能和溶胀性能。结果表明:木棉/ES多孔材料具有良好的成型性及优异的力学性能,采用木棉/ES多孔材料增强聚丙烯酸钠水凝胶后,显著改善了水凝胶的力学性能和溶胀效果;分别用Korsmeyer-Peppas模型和准二级动力学模型研究纯聚丙烯酸钠水凝胶和木棉/ES多孔材料增强水凝胶的溶胀过程,发现Korsmeyer-Peppas模型更适用于纯聚丙烯酸钠水凝胶,而准二级动力学模型更适用于木棉/ES多孔材料增强水凝胶,所得理论平衡溶胀吸水倍率S与实验结果相一致,并且随着NaCl溶液浓度的增加,S实验值越接近理论值。

     

    Abstract: Porous materials with good mechanical properties were prepared using kapok fibers and polyethylene terephthalate fibers (ES) as raw materials through freeze-drying and hot-air bonding processes, and these materials were used as a framework to reinforce sodium polyacrylate hydrogels. The microstructure, mechanical properties, and swelling behavior were investigated. The results showed that kapok/ES porous materials exhibited good moldability and excellent mechanical properties. Reinforcing sodium polyacrylate hydrogel with kapok/ES porous materials significantly improved the mechanical performance and swelling behavior of the hydrogel. The swelling processes of pure sodium polyacrylate hydrogel and kapok/ES porous material-reinforced hydrogels were studied using the Korsmeyer-Peppas model and the pseudo-second-order kinetic model, respectively. It was found that the Korsmeyer-Peppas model was more suitable for pure sodium polyacrylate hydrogel, while the pseudo-second-order kinetic model was more suitable for the kapok/ES porous material-reinforced hydrogel. The theoretical equilibrium swelling ratio S was consistent with the experimental results, and as the concentration of NaCl solution increased, the experimental S values became closer to the theoretical values.

     

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