锌离子电池正极材料复合改性进展

Progress in Composite Modification of Zinc-Ion Battery Cathode Materials

  • 摘要: 锌离子电池(ZIBs)因其高理论容量、高安全性、环境友好及成本低廉等优势,在水系储能领域展现出巨大应用前景。然而,传统正极材料普遍存在本征电导率低、锌离子扩散动力学缓慢、循环过程中结构易坍塌等问题,严重制约其电化学性能。通过构建多组分、多尺度、多界面协同复合体系的电活性物质改性策略,是解决上述瓶颈的有效途径。基于此,从锌离子电池正极材料活性物质组分出发,系统综述了近年来锌电正极材料的结构特性及复合改性方法,重点聚焦嵌入/脱出反应机制及转换反应机制,深入剖析其在提升材料导电性、扩大层间距、稳定晶体结构、优化离子扩散路径、抑制正极材料溶解等方面的关键作用,并对该领域的未来研究方向进行了展望。

     

    Abstract: Zinc-ion batteries (ZIBs) demonstrate significant application potential in aqueous energy storage due to their high theoretical capacity, high safety, environmental friendliness, and low cost. However, conventional cathode materials commonly suffer from low intrinsic conductivity, slow zinc ion diffusion kinetics, and structural collapse during cycling, severely limiting their electrochemical performance. Developing electroactive material modification strategies based on multi-component, multi-scale, and multi-interface synergistic composite systems offers an effective approach to overcome these bottlenecks. Accordingly, this paper systematically reviews the structural characteristics and composite modification methods of zinc-ion battery cathode materials in recent years, focusing on the insertion/extraction reaction mechanism and conversion reaction mechanism. It thoroughly analyzes their key roles in enhancing material conductivity, expanding interlayer spacing, stabilizing crystal structures, optimizing ion diffusion pathways and suppressing cathode material dissolution, while also outlining future development directions in this field.

     

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