纤维素-聚乳酸分子复合策略研究进展

Review of Cellulose-Polylactic acid molecular composite strategy

  • 摘要: 传统石油基塑料制品因难以降解和环境污染问题备受关注。生物聚合物,尤其是聚乳酸(PLA),作为一种可再生的、生物可降解的替代材料,具有巨大的发展潜力。PLA原料来源于植物淀粉和甘蔗等农林副产物,使用后可被自然降解,对环境无害,然而,PLA存在性脆、亲水性差、热稳定性差等缺陷。为克服这些局限,目前的研究中将PLA与纤维素结合,制备性能更优异的复合材料。纤维素-聚乳酸复合材料的制备方法包括熔融共混、使用增容剂、表面改性、原位聚合等,这些方法具体实施工艺、作用机制各不相同。本文将详细介绍纤维素-聚乳酸复合材料的研究背景;聚乳酸材料和纤维素材料的相关基本性质;现有纤维素-聚乳酸复合材料的制备方法的定义、具体实施工艺、复合材料之间各组分的相互作用机理及其优势与缺陷;不同制备工艺得到的纤维素-聚乳酸复合材料的成型、加工、降解性能等重要参数。期望为后续研究工作提供参考。

     

    Abstract: Traditional petroleum based plastic products have attracted much attention due to their difficulty in degradation and environmental pollution issues. Biopolymers, especially polylactic acid (PLA), have great potential for development as a renewable and biodegradable alternative material. PLA raw materials are derived from agricultural and forestry by-products such as plant starch and sugarcane, which can be naturally degraded after use and are harmless to the environment. However, PLA has defects such as brittleness, poor hydrophilicity, and poor thermal stability. To overcome these limitations, current research combines PLA with cellulose to prepare composite materials with superior performance. The preparation methods of cellulose polylactic acid composite materials include melt blending, use of compatibilizers, surface modification, in-situ polymerization, etc. These methods have different specific implementation processes and mechanisms of action. This article will provide a detailed introduction to the research background of cellulose polylactic acid composite materials; The basic properties of polylactic acid materials and cellulose materials; The definition, specific implementation process, interaction mechanism between components of existing cellulose polylactic acid composite materials, as well as their advantages and disadvantages; Important parameters such as molding, processing, and degradation performance of cellulose polylactic acid composite materials obtained by different preparation processes. Expected to provide reference for subsequent research work.

     

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