h-BN增强镓基液态金属复合水凝胶:各向异性导电与拉伸性能研究

h-BN Enhanced Gallium-Based Liquid Metal Composite Hydrogel: A Study on Anisotropic Conductivity and Ultra-Stretchable Properties

  • 摘要: 随着互联网技术尤其是柔性电子的快速发展,可拉伸电子材料在柔性电子产品和可穿戴设备中展现出重要应用前景。本研究提出一种将六方氮化硼(h-BN)与镓基液态金属(GaInSn)混合液体引入聚乙烯醇(PVA)基体中制备高性能复合水凝胶的方法。所得凝胶同时具备优异的力学性能和电学响应特性,所得复合水凝胶同时具有较高的拉伸强度(3.01 MPa)和超大断裂伸长率(可达 847%),其电阻随应变连续变化并保持稳定电学响应,在循环拉伸过程中表现出良好的抗疲劳性。基于该复合凝胶构建的柔性应变传感器能够灵敏捕捉人体关节活动,并呈现清晰且高度可重复的电信号输出。h-BN与GaInSn的协同作用为开发高性能柔性可穿戴应变传感器提供了一种新的材料设计策略。

     

    Abstract: With the rapid development of Internet technology, especially flexible electronics, stretchable electronic materials have shown broad application prospects in flexible electronic products and wearable devices. In this study, a high‑performance composite hydrogel was prepared by incorporating a mixture of hexagonal boron nitride (h‑BN) and gallium‑based liquid metal (GaInSn) into a polyvinyl alcohol (PVA) matrix. The resulting hydrogel exhibits excellent mechanical properties and electrical response. It shows a high tensile strength (3.01 MPa), an ultralarge elongation at break (up to 847%), and a stable, continuous resistance change with strain, as well as good fatigue resistance under cyclic tension. Flexible strain sensors fabricated from this composite hydrogel can sensitively capture human joint motions and produce clear and highly repeatable electrical signals. The synergy of h-BN and GaInSn provides a new material design strategy for the development of high-performance flexible wearable strain sensors.

     

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