含木质素纳米纤维/聚乙烯醇紫外屏蔽复合薄膜制备与性能

Preparation and Properties of UV Shielding Composite Films Containing Lignin Nanofibers/Polyvinyl Alcohol

  • 摘要: 利用竹质含木质素纳米纤维 (LCNF)的高强度和高强度比,向聚乙烯醇(PVA)中引入含木质素纳米纤维,可增强复合膜的力学性能。选用含木质素纳米纤维作为增强相,将纳米纤维和木质素混合后真空抽滤制得含木质素纳米纤维膜,将聚乙烯醇按照不同浓度和厚度进行物理浇筑,制得含木质素纳米纤维/聚乙烯醇复合膜材料。通过含木质素纳米纤维与聚乙烯醇间的氢键作用,复合膜的拉伸强度从75.4 MPa提高至142 MPa。针对复合膜紫外屏蔽的问题,木质素赋予薄膜优异的紫外屏蔽性能,木质素含量为29.5 ± 2.31%时,复合膜对UVA和UVB波段的屏蔽率分别为96.53%和99.9%。含木质素纳米纤维的加入使得复合膜的可见光透过率仍可达78.4%,赋予了复合膜较好光泽、透明度及成像性。含木质素纳米纤维复合薄膜/聚乙烯醇凭借其拉伸强度和紫外屏蔽性能,可用作食品包装、紫外线防护和农用地膜。

     

    Abstract: Utilizing the high strength and high strength - to - mass ratio of lignin - containing cellulose nanofibers (LCNF), the introduction of LCNF into polyvinyl alcohol (PVA) can enhance the mechanical properties of the composite film. LCNF was chosen as the reinforcing phase. After mixing cellulose nanofibers and lignin, the LCNF film was fabricated through vacuum filtration. PVA was physically cast at various concentrations and thicknesses to prepare LCNF/PVA composite film materials. Due to the hydrogen - bonding interaction between LCNF and PVA, the tensile strength of the composite film increased from 75.4 MPa to 142 MPa. Regarding the ultraviolet (UV) shielding issue of the composite film, lignin imparts excellent UV - shielding properties to the film. When the lignin content is 29.5 ± 2.31%, the shielding rates of the composite film for the ultraviolet A (UVA) and ultraviolet B (UVB) bands are 96.53% and 99.9%, respectively. The addition of LCNF enables the visible - light transmittance of the composite film to reach 78.4%, endowing the composite film with good gloss, transparency, and imaging performance. The LCNF/PVA composite film, owing to its high tensile strength and remarkable UV - shielding capabilities, has potential applications in food packaging, UV protection, and agricultural mulch films.

     

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