锂离子电池硅氧负极材料固相预锂化研究进展

Research progress in solid-phase prelithiation of silicon-oxygen anode material for lithium-ion batteries

  • 摘要: 固相预锂化技术因其简单的制备工艺、环境友好性以及出色的预锂化效果已成为硅氧负极材料常用的预锂化方法之一。本文对硅氧材料(SiOx)固相预锂化技术进行了综述,分类介绍了固相预锂化技术采用的锂源,从电化学性能、工艺流程复杂性以及环境友好性等方面对各类固相预锂化技术进行了对比分析。归纳了锂源湿法包覆SiOx以及偏硅酸锂(Li2SiO3)组分调控对固相预锂化性能的提升效果。在此基础之上讨论了现有固相预锂化存在的问题、解决方法以及新的发展方向,并展望了固相预锂化在锂离子电池SiOx中的应用趋势。

     

    Abstract: Solid-phase prelithiation technology has become one of the commonly used prelithiation methods for silicon-oxygen anode materials due to its simple preparation process, environmental friendliness, and excellent prelithiation effect. This paper reviews the solid-phase prelithiation technology for silicon-oxygen materials (SiOx), categorizing the lithium sources used in solid- phase prelithiation techniques. A comparative analysis of various solid-phase prelithiation methods is conducted in terms of electrochemical performance, process complexity, and environmental friendliness. The paper summarizes the enhancement effects of lithium source wet coating on SiOx and the component regulation of lithium metasilicate (Li2SiO3) on solid-phase prelithiation performance. Based on this, it discusses the existing problems, solutions, and new development directions of solid-phase prelithiation technology, and forecasts the application trends of solid-phase prelithiation in SiOx for lithium-ion batteries.

     

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