碱激发矿渣-粉煤灰基地质聚合物固化土力学特性及强度预测

Mechanical properties and strength prediction of alkali activated slag fly ash based geopolymer stabilized soil

  • 摘要: 采用矿渣-粉煤灰基地质聚合物代替水泥进行固化土,应根据各地区可利用工业废弃物产量,工程建设强度需求,因地制宜选用合理的矿渣-粉煤灰基地质聚合物配比。基于此,本文以高炉矿渣(GGBS)和粉煤灰(FA)为原料,水玻璃为碱性激发剂,研究不同高炉矿渣与粉煤灰配比下激发剂模数与掺量、固化材料掺量、养护龄期对地质聚合物固化土强度的影响。试验结果表明:不同GGBS∶FA比所对应的最优水玻璃模数不同,GGBS∶FA=8∶2、6∶4、5∶5依次对应的最优水玻璃模数为1.2,0.9和0.9;不同GGBS∶FA比下地质聚合物固化土所对应的最优激发剂掺量均为15%;在最优激发剂模数与掺量下固化材料为20%时,GGBS∶FA=8∶2、6∶4、5∶5地质聚合物固化土各龄期下强度均高于水泥固化土,养护龄期90 d时地质聚合物固化土强度最高可达16.19 MPa;根据地质聚合物固化土强度与原料比、固化材料掺量以及龄期的关系,建立了可以考虑GGBS∶FA、固化材料掺量和龄期的矿渣-粉煤灰基地质聚合物固化土无侧限抗压强度预测模型,并验证了模型的适用性。通过微观分析发现,水玻璃激发GGBS、FA产生凝胶与土颗粒共同形成骨架结构,增强了地质聚合物固化土强度,提升GGBS在固化材料中的占比可以有效提升地质聚合物固化土强度,其产生的水化硅铝酸钙凝胶(C-(A)-S-H)使土体结构更加密实,而提升FA的占比形成的水化硅铝酸钠凝胶(N-A-S-H)并不能有效黏结土体颗粒提升固化土强度。

     

    Abstract: The use of slag fly ash based geopolymer instead of cement for soil solidification should be based on the available industrial waste production and engineering construction strength requirements in each region, and a reasonable ratio of slag fly ash based geopolymer should be selected according to local conditions. Based on this, this article uses blast furnace slag (GGBS) and fly ash (FA) as raw materials, with sodium silicate as the alkaline activator, to study the effects of activator modulus and dosage, solidification material dosage, and curing age on the strength of geopolymer stabilized soil under different ratios of blast furnace slag and fly ash. The experimental results show that different GGBS: FA ratios correspond to different optimal water glass moduli. The optimal water glass moduli corresponding to GGBS: FA=GGBS∶FA=8∶2, 6∶4, and 5∶5, are 1.2, 0.9, and 0.9, respectively; The optimal dosage of activator for geopolymer stabilized soil under different GGBS: FA ratios is 15%; When the curing material is 20% at the optimal activator modulus and dosage, GGBS∶FA=8∶2, 6∶4, and 5∶5, the strength of geopolymer stabilized soil at all ages is higher than that of cement stabilized soil. At a curing age of 90 days, the highest strength of geopolymer stabilized soil can reach 16.19 MPa; A prediction model for the unconfined compressive strength of slag fly ash based geopolymer stabilized soil was established based on the relationship between the strength of geopolymer stabilized soil and the ratio of raw materials, the dosage of solidified materials, and the age, which can consider GGBS: FA, the dosage of solidified materials, and the age. The applicability of the model was verified. Through microscopic analysis, it is found that sodium silicate stimulates GGBS and FA to produce gel and soil particles to form a skeleton structure together, which enhances the strength of geopolymer stabilized soil. Increasing the proportion of GGBS in the solidified material can effectively improve the strength of geopolymer stabilized soil. The hydrated calcium aluminosilicate gel (C-(A)-S-H) generated by it makes the soil structure more dense, while the hydrated sodium aluminosilicate gel (N-A-S-H) formed by increasing the proportion of FA cannot effectively bond the soil particles to improve the strength of solidified soil.

     

/

返回文章
返回