盾粉/石塑复合材料的制备与力学性能

Preparation and mechanical properties of shield powder/stone-plastic composite materials

  • 摘要: 针对滑石粉成本高、工艺复杂和钢渣产量大但利用率低的问题,采用超细立磨技术结合功能助剂,成功将钢渣加工为中位径(d50)分别为6.445 μm (600目)、5.775 μm (800目)和5.098 μm (1000目)的盾粉。通过熔融共混与热压冷压相结合的工艺实现用盾粉替代滑石粉制备盾粉/石塑复合材料。对其进行拉伸强度、弯曲强度和冲击强度测试,并通过XRD、SEM、FTIR和DSC进行表征分析。结果表明,盾粉的加入显著提升了石塑复合材料的力学性能。尤其是在6.445 μm、5.775 μm和5.098 μm盾粉替代滑石粉比例为50%时,与纯滑石粉/石塑复合材料相比,拉伸强度分别提高12.3%、33.2%和27.4%,弯曲强度分别提高11.7%、26.0%和17.6%,冲击强度分别提高33.3%、52.9%和32.8%。由于,5.775 μm盾粉因其粒径分布宽度最小(2.177),在石塑复合材料中分散性良好,显著提升了界面相容性,因此在提升石塑复合材料力学性能方面表现最为突出。此外,5.775 μm盾粉有效提高了熔融焓和结晶焓,分别为45.16 J·g−1和42.31 J·g−1,这有助于石塑复合材料形成更均匀的晶体结构,并促进成核和晶体生长,从而进一步提升了其力学性能。

     

    Abstract: In response to the high cost and complex processing of talc powder, as well as the large production volume but low utilization rate of steel slag, ultrafine vertical grinding technology combined with functional additives was employed to successfully process steel slag shield powder with a median diameter (d50) of 6.445 μm (600 mesh), 5.775 μm (800 mesh) and 5.098 μm (1000 mesh) respectively. The preparation of shield powder/stone-plastic composite materials were achieved by substituting shield powder for talc powder through a process that integrates melt blending with hot and cold pressing techniques. Tensile strength, bending strength, and impact strength tests were conducted on these materials, and characteristics were analyzed using XRD, SEM, FTIR, and DSC. The results indicate that the incorporation of shield powder significantly enhances the mechanical properties of the stone-plastic composites. Particularly, when the substitution ratio of shield powder for talc powder reaches 50%, the tensile strength is increased by 12.3%, 33.2%, and 27.4%, the bending strength by 11.7%, 26.0%, and17.6%, and the impact strength by 33.3%, 52.9%, and 32.8%, respectively, compared to the composites made with pure talc powder. Due to its narrowest fineness distribution width (2.177), the 5.775 μm shield powder exhibits excellent dispersibility in stone-plastic composite materials and significantly improves interfacial compatibility, thereby demonstrating the most pronounced performance in enhancing the mechanical properties of the stone-plastic composite materials. Additionally, the 5.775 μm shield powder effectively increases the melting enthalpy and crystallization enthalpy to 45.16 J·g−1 and 42.31 J·g−1, respectively, which aids in the formation of a more uniform crystal structure in the stone-plastic composite materials, promotes nucleation and crystal growth, and further enhances their mechanical properties.

     

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