基于墨水直写和熔体浸渗的高强韧耐磨Cu/316L互穿复合材料制备方法及其力学性能

Preparation method and mechanical properties of high-strength, high-toughness, and wear-resistant Cu/316L interpenetrating composites based on ink direct writing and melt infiltration

  • 摘要: 受自然界中天然材料三维互穿结构启发,该工作旨在探索开发兼具高性能与复杂结构的金属基复合材料。采用墨水直写(DIW)技术与无压熔体浸渗工艺结合的方法,成功制备了具有仿生互穿结构的铜/不锈钢(Cu/316L)复合材料。先以DIW技术精确打印出预设构型的多孔316L金属骨架,再利用Cu与316L在高温下优异的润湿性,使熔融Cu在毛细管力驱动下渗入骨架孔隙,形成双相三维互穿的复合结构。研究了不同烧结温度对多孔316L金属骨架微观结构与抗压强度的影响、复合材料的力学性能及耐磨性。结果表明:烧结温度为1200℃时骨架表面相对光滑平整,1400℃时垂直于骨架层叠方向(T方向)加载的抗压强度最大;随着烧结温度增加,骨架表面粗糙度和抗压强度增加;复合材料的力学性能呈显著的各向异性,在T方向加载时,复合材料展现出优异的抗弯强度,且随打印骨架旋转角度的增大而提升;平行于层叠方向(L方向)加载时,抗弯强度有所下降,但不同旋转角度样品间的强度差异相对较小;此外,复合材料展现出良好的耐磨性能。

     

    Abstract: Inspired by the three-dimensional interpenetrating structure of natural materials in nature, this work aimed to explore and develop metal matrix composites that combine high performance with complex structures. A method combining Direct Ink Writing (DIW) technology and pressureless melt infiltration process was employed. First, a porous 316L metal skeleton with a preset configuration was precisely printed using DIW technology. Then, by leveraging the excellent wettability between Cu and 316L at high temperatures, the molten Cu was driven by capillary force to infiltrate into the pores of the skeleton, forming a dual-phase three-dimensional interpenetrating composite structure. The effects of different sintering temperatures on the microstructure and compressive strength of the porous 316L metal skeleton, as well as the mechanical properties and wear resistance of the composite, were investigated. The results showed that at a sintering temperature of 1200℃, the skeleton surface was relatively smooth and flat, while at 1400℃, the maximum compressive strength was achieved when loaded perpendicular to the layer stacking direction (T direction) of the skeleton. As the sintering temperature increased, both the surface roughness and compressive strength of the skeleton increased. The mechanical properties of the composite exhibited significant anisotropy, with excellent flexural strength demonstrated when loaded in the T direction, which increased with the rotation angle of the printed skeleton. When loaded parallel to the layer stacking direction (L direction), the flexural strength decreased, but the strength differences among samples with different rotation angles were relatively small. Additionally, the composite exhibited good wear resistance.

     

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