纳米材料化学改性及阻燃EVA的应用

Chemical Modification of Nanomaterials and Application in Flame-Retardant EVA Composites

  • 摘要: 乙烯-醋酸乙烯酯共聚物(EVA)是一种兼具橡胶弹性和热塑性加工特性的高分子材料,由于其柔韧性好、电绝缘性能优异以及成型加工方便,从而被广泛应用于电线电缆、薄膜和发泡材料等领域。但EVA材料本身可燃性较高,热稳定性较差,这在一定程度上限制了其进一步开发与应用。本文综述了近年来纳米阻燃剂阻燃EVA的研究进展,首先归纳了纳米材料的化学改性方法,包括偶联剂改性法和聚合物接枝法,分析了各自的特点与适用范围;其次总结了纳米复合材料的主要制备技术,包括插层/剥离法、共混法及原位聚合法,对比了不同方法的工艺过程与优缺点;然后阐述了纳米阻燃剂的阻燃机理,重点分析了凝聚相成炭与炭层增强、气相自由基捕获以及气相-凝聚相协同阻燃机制;最后分类介绍了纳米碳基材料、氢氧化物,氧化物、层状硅酸盐粘土在EVA中的阻燃应用与协同效应,总结了各类填料的最佳添加量范围、阻燃效果及优缺点,进一步指出了当前研究面临的挑战,并对未来多功能一体化、智能化、绿色化及数据驱动设计等发展方向进行了展望。本文可为EVA纳米复合材料功能化设计与创新应用提供理论参考。

     

    Abstract: Ethylene-vinyl acetate copolymer (EVA) is a polymeric material that combines the elasticity of rubber with the processing properties of thermoplastics. Due to its good flexibility, excellent electrical insulation properties and ease of moulding, it is widely used in fields such as electrical wires and cables, films and foamed materials. However, EVA itself is highly flammable and has poor thermal stability, which to some extent limits its further development and application. This paper reviews recent research progress on the flame retardancy of EVA using nano-flame retardants. Firstly, it summarises the chemical modification methods for nanomaterials, including coupling agent modification and polymer grafting, analysing the characteristics and scope of application of each; secondly, it summarises the main preparation techniques for nanocomposites, including intercalation/extraction, blending and in-situ polymerisation, comparing the process flows and advantages and disadvantages of different methods; It then elaborates on the flame-retardant mechanisms of nano-flame retardants, focusing on the analysis of carbonisation in the condensed phase and carbon layer reinforcement, free radical scavenging in the gas phase, and synergistic flame-retardant mechanisms between the gas and condensed phases; Finally, the flame-retardant applications and synergistic effects of nanocarbon-based materials, hydroxides, oxides and layered silicate clays in EVA are introduced by category. The optimal loading ranges, flame-retardant performance and advantages and disadvantages of various fillers are summarised, whilst the summarised, whilst the developments, such as multifunctional integration, intelligent design, green manufacturing and data-driven design, are outlined. This paper provides a theoretical reference for the functional design and innovative applications of EVA nanocomposites.

     

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