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多糖-植物蜡-纳米二氧化硅防水防油包装纸制备与性能

朱瑞丰 龙柱 覃程荣 吕文志 郑辉 王志英

朱瑞丰, 龙柱, 覃程荣, 等. 多糖-植物蜡-纳米二氧化硅防水防油包装纸制备与性能[J]. 复合材料学报, 2023, 40(4): 2107-2118. doi: 10.13801/j.cnki.fhclxb.20220622.001
引用本文: 朱瑞丰, 龙柱, 覃程荣, 等. 多糖-植物蜡-纳米二氧化硅防水防油包装纸制备与性能[J]. 复合材料学报, 2023, 40(4): 2107-2118. doi: 10.13801/j.cnki.fhclxb.20220622.001
ZHU Ruifeng, LONG Zhu, QIN Chengrong, et al. Preparation and performance of water and oil-resistant packaging paper based on polysaccharide-vegetable wax-nano-SiO2[J]. Acta Materiae Compositae Sinica, 2023, 40(4): 2107-2118. doi: 10.13801/j.cnki.fhclxb.20220622.001
Citation: ZHU Ruifeng, LONG Zhu, QIN Chengrong, et al. Preparation and performance of water and oil-resistant packaging paper based on polysaccharide-vegetable wax-nano-SiO2[J]. Acta Materiae Compositae Sinica, 2023, 40(4): 2107-2118. doi: 10.13801/j.cnki.fhclxb.20220622.001

多糖-植物蜡-纳米二氧化硅防水防油包装纸制备与性能

doi: 10.13801/j.cnki.fhclxb.20220622.001
基金项目: 广西大学清洁化制浆造纸与污染控制重点实验室开放基金(2019KF03);贵州省科技厅科技支撑计划项目(20192860);贵州省教育厅普通高等学校科技拔尖人才支持计划项目(2018079)
详细信息
    通讯作者:

    龙柱,博士,教授,博士生导师,研究方向为高性能纸基功能材料、生物基化学品和生物质综合利用 E-mail: longzhu@jiangnan.edu.cn

  • 中图分类号: TB332

Preparation and performance of water and oil-resistant packaging paper based on polysaccharide-vegetable wax-nano-SiO2

Funds: Open Foundation for Key Laboratory of Clean Pulp and Paper and Pollution Control, Guangxi University (2019KF03); Science and Technology Support Program of Science and Technology Department of Guizhou Province (20192860); Top Science and Technology Talents Support Program of Guizhou Provincial Education Department (2018079)
  • 摘要: 随着社会的发展,人们对无毒环保食品包装材料的需求不断增加。现阶段,兼顾防水防油性能的无氟食品包装纸研究较少。本文以壳聚糖溶液与海藻酸钠溶液为原料,通过阿魏酸交联制备复合防油剂,并涂布在食品包装原纸上,制备防油纸;然后以巴西棕榈蜡与纳米二氧化硅为原料,制备复合防水剂,采用浸渍的方法,制备防水防油纸,探究不同配比及涂布量对纸张防水防油效果与纸张性能的影响。结果表明:当壳聚糖与海藻酸钠复配质量比为8∶2、涂布量为4 g/m2时,防油纸可达到最高防油等级(12级);当巴西棕榈蜡与纳米二氧化硅复配质量比为4∶3、浸渍量为3 g/m2时,纸张表面吸水量(Cobb)值为5.93 g/m2,水接触角为158.40°,显著提升了原纸的防油性能与防水性能。此外,与未涂布纸相比,防水防油纸的抗张强度提升了30%,透气度下降了60%。本文制备工艺简单、原材料无氟环保、纸张防水防油性能较好,有望在食品包装得到应用。

     

  • 图  1  多糖-植物蜡-纳米二氧化硅(CS-SA-CW-HSNPs)防水防油纸制备流程

    Figure  1.  Preparation process of polysaccharide-vegetable wax-nano-SiO2 (CS-SA-CW-HSNPs) water and oil-resistant paper

    CS—Chitosan; SA—Sodium alginate; CW—Carnauba wax; HSNPs—Hydrophobic silica nano particles

    图  2  (a) 不同浸渍量CW-HSNPs防水纸表面吸水量(Cobb)值与水接触角(WCA);(b) 不同质量比CS-SA防油涂层黏度

    Figure  2.  (a) Cobb value and water contact angle (WCA) of CW-HSNPs water-resistant paper with different dipping amounts; (b) Viscosity of CS-SA oil-resistant coating with different mass ratios

    图  3  (a) 不同质量比CS-SA防油纸防油等级;(b) 涂布量对纸张防油性能的影响

    Figure  3.  (a) Oil resistance grade of CS-SA oil-resistant paper with different mass ratios; (b) Influence of coating amounts on oil resistance of paper

    图  4  不同质量比防水防油纸的厚度 (a)、透气度 (b) 和抗张强度 (c);(d) 原纸与防水防油纸润湿性能

    Figure  4.  Thickness (a), air permeability (b) and tensile strength (c) of different mass ratios of water and oil-resistant paper; (d) Wetting properties of base paper and water and oil-resistant paper

    OCA—Oil contact angle

    图  5  原纸、防油纸、防水防油纸水蒸气透过率 (a) 与油脂吸收率 (b)

    Figure  5.  Water vapor transmission rate (WVTR) (a) and oil absorption rate (b) of base paper, oil-resistant paper and water and oil-resistant paper

    图  6  原纸、防油纸和防水防油纸FTIR图谱

    Figure  6.  FTIR spectra of base paper, oil-resistant paper and water and oil-resistant paper

    图  7  原纸 (a)、防油纸 (b) 和防水防油纸 (c) 的SEM图像和对应的截面图 ((d)~(f))

    Figure  7.  SEM images of base paper (a), oil-resistant paper (b) and water and oil-resistant paper (c) and corresponding sectional view ((d)-(f))

    图  8  原纸 (a)、防油纸 (b) 和防水防油纸 (c) 的AFM图像

    Figure  8.  AFM images of base paper (a), oil-resistant paper (b) and water and oil-resistant paper (c)

    图  9  原纸、防油纸和防水防油纸TG曲线 (a) 与DTG曲线 (b)

    Figure  9.  TG (a) and DTG (b) curves of base paper, oil-resistant paper and water and oil-resistant paper

    图  10  大豆油 ((a), (b))、薯条 ((c), (d))、可乐 ((e), (f)) 对原纸和防水防油纸的渗透效果

    Figure  10.  Penetration effect of soybean oil ((a), (b)), french fries ((c), (d)) and cola ((e), (f)) on base paper and water and oil-resistant paper

    表  1  测试液体表面能($ {\gamma }_{{\rm{l}}} $)的极性分量($ {\gamma }_{{\rm{l}}}^{{\rm{h}}} $)与色散分量($ {\gamma }_{{\rm{l}}}^{{\rm{d}}} $)

    Table  1.   Dispersion component ($ {\gamma }_{{\rm{l}}}^{{\rm{d}}} $) and polar component ($ {\gamma }_{{\rm{l}}}^{{\rm{h}}} $) of the surface energy ($ {\gamma }_{{\rm{l}}} $) in the test liquid

    Liquid$ {\gamma }_{{\rm{l}}}^{{\rm{d}}} $/(J·m−2)$ {\gamma }_{{\rm{l}}}^{{\rm{h}}} $ /(J·m−2)$ {\gamma }_{{\rm{l}}} $/(J·m−2)
    H2O0.02180.05100.0728
    CH2I20.04850.00230.0508
    下载: 导出CSV

    表  2  CW-HSNPs工艺探究

    Table  2.   CW-HSNPs process research results

    SampleCW/%HSNPs/%Cobb/(g·m−2)WCA/(°)
    CW-HSNPs-1 1.0 1.0 11.22 140.20
    CW-HSNPs-2 1.0 1.5 8.86 147.60
    CW-HSNPs-3 1.0 2.0 7.70 150.30
    CW-HSNPs-4 2.0 1.0 8.39 148.40
    CW-HSNPs-5 2.0 1.5 5.93 158.40
    CW-HSNPs-6 2.0 2.0 5.86 158.60
    CW-HSNPs-7 3.0 1.0 8.29 148.50
    CW-HSNPs-8 3.0 1.5 5.90 158.50
    CW-HSNPs-9 3.0 2.0 5.84 158.60
    Note: WCA—Water contact angle; Cobb—Water absorption of paper surface.
    下载: 导出CSV

    表  3  未涂布纸与涂布纸表面能($ {\gamma }_{{\rm{l}}} $)中极性分量($ {\gamma }_{{\rm{l}}}^{{\rm{h}}} $)与色散分量($ {\gamma }_{{\rm{l}}}^{{\rm{d}}} $)

    Table  3.   Polar component ($ {\gamma }_{{\rm{l}}}^{{\rm{h}}} $) and dispersion component ($ {\gamma }_{{\rm{l}}}^{{\rm{d}}} $) of the surface energy ($ {\gamma }_{{\rm{l}}} $) of uncoated and coated paper

    Sample$ {\gamma }_{{\rm{l}}}^{{\rm{d}}} $/(J·m−2)$ {\gamma }_{{\rm{l}}}^{{\rm{h}}} $/(J·m−2)$ {\gamma }_{{\rm{l}}} $/(J·m−2)
    Uncoated0.03740.01300.0504
    Coated0.01640.00900.0254
    下载: 导出CSV
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  • 收稿日期:  2022-04-28
  • 修回日期:  2022-06-03
  • 录用日期:  2022-06-11
  • 网络出版日期:  2022-06-22
  • 刊出日期:  2023-04-15

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