石墨烯/碳纳米管杂化碳纤维织物复合材料的力学、导电和雷击性能

Mechanical properties, electrical conductivities and lightning strike damage behaviors of CNT/graphene modified carbon fabric reinforced composites

  • 摘要: 利用涂覆法制备了碳纳米管(CNT)改性和CNT与多层石墨烯(MLG)共改性的织物及其复合材料。力学性能研究表明,织物CNT杂化对复合材料的力学性能影响较小,而织物CNT/MLG共杂化后复合材料层间剪切强度下降了41.6%。导电性研究表明,CNT杂化和CNT/MLG共杂化的织物导电性分别提高了7.78%和10.2%,相应的复合材料厚度向电导率(σz)分别提高了472%和124%,达到0.79 S/cm和0.31 S/cm,面内电导率分别提高43.2%和17.8%。2A区雷击损伤研究表明,CNT杂化织物复合材料分层损伤面积和损伤深度分别为240 mm2和0.343 mm,相比对比样降低了62.3%和35%。CNT/MLG共杂化织物复合材料的分层损伤面积扩大了79.3%,但损伤深度降低了42.2%。作为对比,调降σz至0.011 S/cm的对比样分层损伤面积大幅扩大到30.5倍,损伤深度提高了150%。机制分析表明,这类复合材料σz的提高同时降低了分层损伤面积和损伤深度,而织物层导电性的提高降低了损伤深度,但扩大了浅表层的分层损伤面积。

     

    Abstract: By coating aqueous dispersions of carbon nanotubes (CNTs) and multilayer graphene (MLGs) on the carbon fiber (CF) fabrics, CNT-hybrid and CNT-MLG co-hybrid fabrics and their composites were prepared. The mechanical studies show that CNT hybridization only has little effect on the mechanical properties of the composites, while CNTs-MLGs co-hybridization caused a 41.6% decrease of the interlaminar shear strength. The conductivity studies show that the conductivities of the CNT and CNT/MLG hybrid fabrics increased by 7.78% and 10.2%, respectively. The conductivities through thickness direction (σz) of the corresponding composites increased by 472% and 124% compared to the control, reaching 0.79 S/cm and 0.31 S/cm, respectively. Their in-plane conductivities increased by 43.2% and 17.8%, respectively. The lightning strike damage (LSD) studies in Zone 2A show that the delamination area and damage depth of the CNT hybrid composite are 240 mm2 and 0.343 mm, which decreased by 62.3% and 35%. The delamination area of CNT/MLG co-hybrid fabric composite increased by 79.3%, while its damage depth reduced by 42.2%. As a comparison, the delamination area of the another control with a low σz of 0.011 S/cm significantly increased to 30.5 times and its damage depth increased by 150%. Mechanism analysis shows that for this kind of composites, the increase in σz reduced both the delamination area and damage depth, while the increase in fabric conductivity reduced the damage depth but expands the delamination area in the shallow layer.

     

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